ArticleNational science review2025
Radical-activable charge-transfer cocrystals for solar thermoelectric generator toward information conversion.
Article in National science review, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
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Who cites it
4 citing papers in PubMed.
- Organic Charge-Transfer Dielectric Cocrystals for Flexible Triboelectric Nanogenerators and Wearable Application.Small (Weinheim an der Bergstrasse, Germany) · 2026Article
- Photochromism-Driven Full Solar Spectrum Absorption for Efficient Photo-Thermo-Electric Conversion.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Two-dimensional organic-inorganic molecular cocrystal.National science review · 2026Article
- When cocrystals become radical-activable.National science review · 2025Article
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Authors and funding
16 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Solar thermoelectric generators (STEGs) that can effectively harvest solar energy and convert it into affordable electricity, provide a promising solution for self-powered wearable electronics and the Internet of Things (IoT). However, their electricity generation is often limited by the low thermal concentration or unstable temperature gradients in practical applications. Herein, we rationally designed an organic radical-activable charge-transfer (CT) cocrystal based on the open-shell radical electron acceptor of 2,6-dibromonaphthalene-1,4,5,8-tetracarboxylic dianhydride. The open-shell radical contributes to the strong near-infrared absorption and nonradiative recombination, resulting in a high photothermal conversion efficiency of 67.2% for the prepared CT cocrystal. Furthermore, the photothermal ink containing the radical-activable CT cocrystal and the transparent resin was successfully coated onto a thermoelectric generator as a cost-effective light absorber, facilely forming a high-performance STEG. Notably, the prepared STEG output a voltage of 143 mV under 1 sun irradiation, demonstrating real-time photodetection capability. We anticipate the potential applications of these cocrystals in self-powered optoelectronics, such as a non-contact and long-distance information converters.
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Registered trials
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