Evidence map›Paper›PMID 40333846›Full record

ArticleMolecules (Basel, Switzerland)2025

Mechanochemical Sequential Deoxygenative Cross-Coupling Reactions of Phenols Under Ruthenium-Nickel Catalysis.

Satenik Mkrtchyan, Vishal B Purohit, Michał Jakubczyk, Vaibhav D Prajapati, Ronak V Prajapati, Michael G Garcia, Eugene Karpun, Vitaliy Yepishev, Manoj K Saini, Sehrish Sarfaraz and 4 more

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Molecules (Basel, Switzerland), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

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2 · The registry

The trial behind it

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3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

14 authors.

Satenik MkrtchyanDepartment of Chemistry, Faculty of Natural Sciences, Matej Bel University, Tajovskeho 40, 974 01 Banska Bystrica, Slovakia.
Vishal B PurohitDepartment of Chemical Sciences, P. D. Patel Institute of Applied Sciences, Charotar University of Science and Technology (CHARUSAT), Changa 388421, Gujarat, India.ORCID 0000-0002-9392-8136
Michał JakubczykInstitute of Inorganic Chemistry, Czech Academy of Sciences, Husinec-Rez c.p. 1001, 250 68 Husinec-Rez, Czech Republic.ORCID 0000-0002-6277-5800
Vaibhav D PrajapatiShri Alpesh N. Patel Post Graduate Institute of Science & Research, Anand 388001, Gujarat, India.ORCID 0000-0002-0389-5925
Ronak V PrajapatiDepartment of Chemistry, Sardar Patel University, Vallabh Vidyanagar 388120, Gujarat, India.ORCID 0000-0002-6945-6925
Michael G GarciaDepartment of Biology/Chemistry, Center for Cellular Nanoanalytics (CellNanOs), University Osnabruck, Barbarastr. 7, D-49076 Osnabruck, Germany.
Eugene KarpunLife Chemicals Ukraine, Winston Churchill St. 5, 02000 Kyiv, Ukraine.ORCID 0000-0003-1816-812X
Vitaliy YepishevLife Chemicals Ukraine, Winston Churchill St. 5, 02000 Kyiv, Ukraine.
Manoj K SainiDepartment of Chemistry, Institute of Science, Banaras Hindu University, Varanasi 221005, Uttar Pradesh, India.ORCID 0000-0003-2142-8578
Sehrish SarfarazDepartment of Chemistry, COMSATS University, Abbottabad Campus, Abbottabad 22060, KPK, Pakistan.
Khurshid AyubDepartment of Chemistry, COMSATS University, Abbottabad Campus, Abbottabad 22060, KPK, Pakistan.
Gabriela AddováDepartment of Organic Chemistry, Faculty of Natural Sciences, Comenius University in Bratislava, Ilkovicova 6, 842 15 Bratislava, Slovakia.ORCID 0000-0003-3534-309X
Juraj FiloDepartment of Organic Chemistry, Faculty of Natural Sciences, Comenius University in Bratislava, Ilkovicova 6, 842 15 Bratislava, Slovakia.ORCID 0000-0002-3995-2565
Viktor O IaroshenkoDepartment of Chemistry, Faculty of Natural Sciences, Matej Bel University, Tajovskeho 40, 974 01 Banska Bystrica, Slovakia.ORCID 0000-0002-5647-5326

Funding

The Slovak Research and Development Agency APVV-21-0362
6 · The paper itself

Abstract

Herein, we report the first mechanochemical strategy for the Ru-catalyzed deoxygenative borylation of free phenols via C-O bond cleavage. This Ru-catalyzed phenolic borylation approach has been successfully extended to the Suzuki-Miyaura-type cross-coupling of phenols with aryl bromides. The protocol accepts a wide scope of phenolic substrates, allowing the synthesis of aryl pinacolboranes and biphenyl structures in excellent yields and serving as a better alternative to classical cross-coupling reactions in the context of pot, atom, and step economy synthesis.

Indexed as

borylationmechanochemistryphenolsrutheniumSuzuki–Miyaura-type cross-coupling

Identifiers

PMID40333846
PMCPMC12029765

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