ArticleInorganic chemistry2025
Hydrogen-Bond-Assisted Chalcogen Transfer between Phosphine Selenides and Arsine Oxides.
Article in Inorganic chemistry, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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6 authors.
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Abstract
The Brønsted acid catalysis is widely regarded as one of the most effective methods for activating inert substrates and enabling unique reactivity. In this work, we introduce the first example of H-bond-assisted chalcogen exchange between arsine oxides and phosphine selenides under mild conditions, providing a powerful approach to the synthesis of arsine selenides. The reaction proceeds successfully in both protic and aprotic solvents and is accelerated by the presence of any nonaqueous acid. This newly discovered reaction is tested for various arsine oxides R
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