Evidence map›Paper›PMID 40316551›Full record

ArticleNature communications2025

Building lactams by highly selective hydrodeoxygenation of cyclic imides using an alumina-supported AgRe bimetallic nanocatalyst.

Carles Lluna-Galán, Juan Camilo Arango-Daza, Daviel Gómez, Patricia Concepción, Rong Sun, Jose J Calvino, Laura Simonelli, Rosa Adam, Jose R Cabrero-Antonino

Abstract read
In one paragraph

Article in Nature communications, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Article
  2. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors.

Carles Lluna-GalánInstituto de Tecnología Química. Universitat Politècnica de València-Consejo Superior Investigaciones Científicas (UPV-CSIC). Avda. de los Naranjos s/n, València, 46022, Spain.ORCID http://orcid.org/0000-0003-1761-9275
Juan Camilo Arango-DazaInstituto de Tecnología Química. Universitat Politècnica de València-Consejo Superior Investigaciones Científicas (UPV-CSIC). Avda. de los Naranjos s/n, València, 46022, Spain.ORCID http://orcid.org/0000-0002-8209-0622
Daviel GómezInstituto de Tecnología Química. Universitat Politècnica de València-Consejo Superior Investigaciones Científicas (UPV-CSIC). Avda. de los Naranjos s/n, València, 46022, Spain.ORCID http://orcid.org/0000-0003-0010-4507
Patricia ConcepciónInstituto de Tecnología Química. Universitat Politècnica de València-Consejo Superior Investigaciones Científicas (UPV-CSIC). Avda. de los Naranjos s/n, València, 46022, Spain.
Rong SunDepartamento de Ciencia de los Materiales e Ingeniería Metalúrgica y Química Inorgánica, Facultad de Ciencias, Universidad de Cádiz. Puerto Real, Cádiz, 11510, Spain.
Jose J CalvinoDepartamento de Ciencia de los Materiales e Ingeniería Metalúrgica y Química Inorgánica, Facultad de Ciencias, Universidad de Cádiz. Puerto Real, Cádiz, 11510, Spain.ORCID http://orcid.org/0000-0002-0989-1335
Laura SimonelliCELLS-ALBA Synchrotron Radiation Facility. Cerdanyola del Vallès, Barcelona, 08390, Spain.ORCID http://orcid.org/0000-0001-5331-0633
Rosa AdamDepartament de Química Orgànica, Facultat de Farmàcia, Universitat de València, Av. Vicent Andrés Estellés s/n, Burjassot, València, 46100, Spain. rosa.adam@uv.es.ORCID http://orcid.org/0000-0001-9392-7187
Jose R Cabrero-AntoninoInstituto de Tecnología Química. Universitat Politècnica de València-Consejo Superior Investigaciones Científicas (UPV-CSIC). Avda. de los Naranjos s/n, València, 46022, Spain. jcabrero@itq.upv.es.ORCID http://orcid.org/0000-0001-9628-9803

Funding

Generalitat Valenciana (Regional Government of Valencia) MFA/2022/016Generalitat Valenciana (Regional Government of Valencia) PROMETEO/2021/077Generalitat Valenciana (Regional Government of Valencia) SEJI/2019/006Generalitat Valenciana (Regional Government of Valencia) SEJI/2020/013la Caixa Foundation (Caixa Foundation) LCF/BQ/PI18/11630023
6 · The paper itself

Abstract

The rational design of robust nanocatalysts containing the suitable active sites for building relevant organic compounds, such as lactams, is a desired approximation towards the development of a sustainable fine chemistry field. In that sense, the design of a proper nanomaterial able to mediate the selective hydrodeoxygenation of cyclic imides to lactams with high tolerance to the preservation of aromatic rings remains rather unexplored. Here, we show the design of a bimetallic AgRe nanomaterial with notable activity and selectivity to mediate this transformation affording more than 60 lactams from the corresponding imides. Interestingly, in this work we disclose that the optimal AgRe nanocatalyst is constituted by AgReO

Identifiers

PMID40316551
PMCPMC12048504

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.