ArticleProceedings of the National Academy of Sciences of the United States of America2025
Stereoselective construction of coconformational mechanically helical and topologically chiral [2]catenanes induced by point chirality.
Article in Proceedings of the National Academy of Sciences of the United States of America, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
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Who cites it
4 citing papers in PubMed.
- Stereoselective Synthesis of Topologically Chiral Knots and Links: Synthesis and Applications.Molecules (Basel, Switzerland) · 2026Review
- Observation of Near-Infrared Photothermal and Photoacoustic Effects in a Metallosupramolecular Trefoil Knot.Angewandte Chemie (International ed. in English) · 2025Article
- Rocking (and Shuttling) in a Nanosized Metallobox.Angewandte Chemie (International ed. in English) · 2025Article
- Stereoselective construction of coconformational mechanically helical and topologically chiral [2]catenanes induced by point chirality.Proceedings of the National Academy of Sciences of the United States of America · 2025Article
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Authors and funding
4 authors.
Funding
Abstract
Supported by chiral stationary phase high-performance liquid chromatography HPLC (CSP-HPLC), examples of chiral mechanically interlocked organic molecules, including knots, rotaxanes, and catenanes, have been reported. However, the exploration of stereoselective construction of chiral cationic complexes, particularly those induced by point chirality, has been notably limited due to the constraints posed by the type of chiral chromatographic columns and separation efficiency. To address this, we have developed a construction strategy for generating coconformational mechanically helical and topologically chiral [2]catenanes through the induction of point chirality. In this study, by adjusting the symmetry of the ligand, we have easily realized the efficient construction of high-yield crystalline coconformational mechanically helical and topologically chiral [2]catenanes. Moreover, within the enantiomerically pure chiral environment of molecular self-assembly driven by
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