Evidence map›Paper›PMID 40305221›Full record

ArticleThe Journal of organic chemistry2025

Water Effect on the Photochemistry of Arylazo Sulfonates.

Luca Nicchio, Hawraz Ibrahim M Amin, Stefano Genualdo, Stefano Protti, Maurizio Fagnoni

Abstract read
In one paragraph

Article in The Journal of organic chemistry, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Article
  2. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors.

Luca NicchioPhotoGreen Lab, Department of Chemistry, University of Pavia, Viale Taramelli 12, 27100 Pavia, Italy.ORCID 0000-0002-8467-2589
Hawraz Ibrahim M AminPhotoGreen Lab, Department of Chemistry, University of Pavia, Viale Taramelli 12, 27100 Pavia, Italy.
Stefano GenualdoPhotoGreen Lab, Department of Chemistry, University of Pavia, Viale Taramelli 12, 27100 Pavia, Italy.
Stefano ProttiPhotoGreen Lab, Department of Chemistry, University of Pavia, Viale Taramelli 12, 27100 Pavia, Italy.ORCID 0000-0002-5313-5692
Maurizio FagnoniPhotoGreen Lab, Department of Chemistry, University of Pavia, Viale Taramelli 12, 27100 Pavia, Italy.ORCID 0000-0003-0247-7585

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The effect of water on visible-light-driven generation of aryl radicals or aryl cations from colored shelf-stable arylazo sulfonates has been investigated. Photoinduced ionic and radical decomposition of these salts compete, depending on the media used. In organic solvents, light-induced homolysis of the N-S bond occurs, and the resulting aryl radical may be used to some extent for arylation reactions. On the contrary, in neat water, radical chemistry is prevented by an efficient photoheterolysis, and a reactive aryl cation is otherwise generated.

Identifiers

PMID40305221
PMCPMC12117561

What OpenQuestion holds

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LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.