ArticleAngewandte Chemie (International ed. in English)2025
N-Insertion of Diazonium Salts Into Ketone Derivatives.
Article in Angewandte Chemie (International ed. in English), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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Who cites it
3 citing papers in PubMed.
- Theoretical Investigation on the Mechanism of NiJACS Au · 2026Article
- Skeletal Editing via Diastereoselective Ring Expansion Enables Enantioenriched Tetrasubstituted ΔJACS Au · 2026Article
- N-Insertion of Diazonium Salts Into Ketone Derivatives.Angewandte Chemie (International ed. in English) · 2025Article
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Authors and funding
4 authors.
Funding
Abstract
We report a new oxidative nitrogen insertion into cyclic ketones using readily available diazonium salts. In the case of indanones, the reaction is promoted by auto-catalytically generated Brønsted acid and proceeds via sequential α-diazenylation and ring expansion through an N-iminoaziridinium intermediate. For less α-acidic ketones, a complementary strategy employing silyl enol ethers was developed: catalyzed by HNTf
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Registered trials
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