ReviewPolymers2025
Incorporation of Carbocyclic Moieties into Polymer Structure: A Powerful Way to Polymers with Increased Microporosity.
Review in Polymers, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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3 authors.
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Abstract
Microporous soluble polymers attract great attention as materials for membrane gas separation, gas storage and transportation, as sorbents, supports for catalysts, and matrices for mixed matrix membranes. The key problems in the development of this area of polymer chemistry include the search for methods of controlling the porous structure parameters and ensuring the stability of their properties over time. In this connection, a fruitful approach is to introduce bulky and rigid, often framework carbocyclic moieties into the polymer backbones and side chains. This review discusses the effect of carbocyclic moieties on gas transport properties, BET surface area, and FFV of glassy polymers, such as polyacetylenes, polynorbornenes, polyimides, and ladder and partially ladder polymers. In the majority of cases, the incorporation of carbocyclic moieties makes it possible to controllably increase these three parameters. Carbocyclic moieties can also improve CO
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