ArticleCommunications chemistry2025
Axial chirality-induced rigidification in aminoboranes enhances persistent room-temperature phosphorescence and circularly polarized luminescence.
Article in Communications chemistry, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
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5 citing papers in PubMed.
- Decoding circular polarization with biaxially chiral fluorescence reporters.Chemical science · 2026Article
- Engineering LE-CT State Synergy in Aminoboranes for Single Molecule White Light Emission and Dual-Mode Chiroptical/Phosphorescence Output.Angewandte Chemie (International ed. in English) · 2026Article
- Aggregated-state arylborane-pillar[5]arenes: a new three-in-one method for the modulation of circularly polarized luminescence.Chemical science · 2026Article
- Boosting Red Room-Temperature Phosphorescence by Host-Guest Confinement: Acrylonitrile Derivatives in PMMA Toward Long-Lived Afterglow and Anti-Counterfeiting.Luminescence : the journal of biological and chemical luminescence · 2026Article
- Luminescent Chiral Molecular Glasses by Melt-Quenching Enantiopure BINAP.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
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7 authors.
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Abstract
Long-lived triplet exciton harvesting materials are of immense interest for applications in bioimaging, optoelectronics, anticounterfeiting, and sensing. However, achieving persistent room-temperature phosphorescence (pRTP) in metal-free systems remains a significant challenge. Herein, we present purely organic axially chiral aminoboranes (R/S-(BN)₂) with enhanced pRTP properties and circularly polarized luminescence (CPL). By introducing axial chirality, the dual-core (R/S-(BN)₂) system achieves steric-hindrance-caused rigidity, which restricts molecular motions, leading to superior phosphorescence properties. Notably, R-(BN)₂ demonstrates a phosphorescence quantum yield (Φ
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