ArticleAdvanced materials (Deerfield Beach, Fla.)2025
Developing Quasi-Solid-State Ether-Based Electrolytes with Trifluorotoluylation Ionic Liquids for High Voltage Lithium Metal Batteries.
Article in Advanced materials (Deerfield Beach, Fla.), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
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Who cites it
4 citing papers in PubMed.
- Dual Interlocked Mediators Enable Single-Ion-Conducting Quasi-Solid-State Electrolytes for Ultrafast-Charging Long-Life Sodium Metal Batteries.Nano-micro letters · 2026Article
- High energy density quasi-solid-state lithium batteries usingChemical science · 2026Review
- Electrolyte/electrode interphase regulation with methylthiolation ionic liquids for high-voltage quasi-solid-state Li metal batteries.Science advances · 2025Article
- Developing Quasi-Solid-State Ether-Based Electrolytes with Trifluorotoluylation Ionic Liquids for High Voltage Lithium Metal Batteries.Advanced materials (Deerfield Beach, Fla.) · 2025Article
Corrections and comments
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Authors and funding
10 authors.
Funding
Abstract
The practical application of quasi-solid-state ether-based electrolytes is hindered by lithium dendrite formation and poor oxidation stability, which reduce the cycle life and energy density of the battery. Here, taking advantage of the ionic liquids' high ionic interactions and structural flexibility in forming an optimized electrode/electrolyte interface, a pyrrolidinium-based ionic liquids with trifluorotoluylation cationic segment is designed and developed. The oxidation of anions in the electrolytes is induced to form a robust inorganic LiF-rich interphase at the cathode, thereby effectively achieving high oxidation stability and suppressing the dissolution of transition metal ions. In addition, the LiF interphases derived from the trifluorotoluylation cations increase the modulus of the anode interface and suppress the growth of lithium dendrites. Therefore, the Li-LiFePO
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Registered trials
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