ArticleScientific reports2025
Structural and electrochemical properties of ternary solid polymer electrolytes based on PVA:CS:FSG doped with sodium thiocyanate.
Article in Scientific reports, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
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Abstract
Biodegradable solid polymer electrolytes (BSPEs) have gained significant attention due to their exceptional processability, safety, and flexibility. This work presents the development of sodium ion (Na +) conducting ternary blended (BSPEs) using a standard solution casting technique. Fourier transform infrared spectroscopy (FTIR) and X-ray diffraction (XRD) validated the complete salt dissociation and demonstrated the formation of polymer-salt complexes. The deconvoluted XRD spectra revealed the degree of crystallinity ([Formula: see text]) of electrolytes where the sample incorporated 40 wt% of NaSCN salt content (STC4) was found to be the lowest [Formula: see text] value. The deconvoluted FTIR spectra were used to estimate ionic transport parameters of diffusion coefficient ([Formula: see text]), ion mobility (μ), and carrier density ([Formula: see text]). Ionic conductivity and electrical properties of electrolyte samples were investigated by electrochemical impedance spectroscopy (EIS). The EIS results were fitted with electrical equivalent circuits to understand the electrical behavior of the films. The highest DC conductivity value ([Formula: see text]) of (2.74 × 10
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