ArticleAngewandte Chemie (International ed. in English)2025
Coordinative Ring-Opening Polymerization of Limonene Carbamate Toward Phosgene- and Isocyanate-Free Polyurethane.
Article in Angewandte Chemie (International ed. in English), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
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Who cites it
2 citing papers in PubMed.
- Coordinative Ring-Opening Copolymerization of Limonene Carbamate and ε-Caprolactone Toward Phosgene- and Isocyanate-Free Polyesterurethane Block-Copolymers with Tunable Properties.Macromolecular rapid communications · 2026Article
- Coordinative Ring-Opening Polymerization of Limonene Carbamate Toward Phosgene- and Isocyanate-Free Polyurethane.Angewandte Chemie (International ed. in English) · 2025Article
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5 authors.
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Abstract
This study presents a phosgene- and isocyanate-free route for the synthesis of polyurethanes using (R)-limonene as a bio-based starting material. The synthesis of the cyclic limonene-based carbamate monomer LU is achieved in high yields using dimethyl carbonate as a sustainable, less hazardous phosgene surrogate and is verified by NMR, SC-XRD, ESI-MS, GC-MS, and elemental analysis. Polymerizations were carried out by coordinative ring-opening polymerization. Sn(Oct)
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