Evidence map›Paper›PMID 40273106›Full record

ArticleProceedings of the National Academy of Sciences of the United States of America2025

Disentangling conduction pathways at the ionic-electronic interface in EMI-TFSI-covered graphene transistors.

Mathieu Lizée, Ali Esfandiar, Eva Panoni, Artem Mischenko, Pierre-Louis Taberna, Patrice Simon, Lydéric Bocquet

Abstract read
In one paragraph

Article in Proceedings of the National Academy of Sciences of the United States of America, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Mathieu LizéeLaboratoire de Physique de l'École Normale Supérieure, Paris 75005, France.ORCID 0000-0003-2497-3336
Ali EsfandiarLaboratoire de Physique de l'École Normale Supérieure, Paris 75005, France.ORCID 0000-0002-7566-9791
Eva PanoniLaboratoire de Physique de l'École Normale Supérieure, Paris 75005, France.ORCID 0009-0005-9860-2257
Artem MischenkoDepartment of Physics and Astronomy, University of Manchester, Manchester M13 9PL, United Kingdom.
Pierre-Louis TabernaUniversité Toulouse III Paul Sabatier Centre Interuniversitaire de Recherche et d'Ingénierie des Matériaux Laboratory UMR CNRS 5085, Toulouse 31062, France.
Patrice SimonUniversité Toulouse III Paul Sabatier Centre Interuniversitaire de Recherche et d'Ingénierie des Matériaux Laboratory UMR CNRS 5085, Toulouse 31062, France.
Lydéric BocquetLaboratoire de Physique de l'École Normale Supérieure, Paris 75005, France.ORCID 0000-0003-3577-5335

Funding

EC | European Research Council (ERC) 101071937
6 · The paper itself

Abstract

Transport of electrons and ions at carbon surfaces immersed in electrolytes is instrumental for a wide variety of membrane processes as well as energy storage in batteries and supercapacitors. Ion transport in a nanoporous electrode strongly depends on its electronic conductance and on the interfacial capacitance with the electrolyte. In this study, we use in-plane impedance spectroscopy to disentangle in-plane ionic and electronic transport on a single crystal graphene transistor covered by an ionic liquid droplet (1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide, EMI-TFSI). droplet. Due to the atomic thickness of graphene combined to the strong affinity of EMI+ for carbon, this transistor maximizes ion-electron couplings. Using gate- and temperature-dependent in-plane spectroscopy, we extract both the electronic and ionic conductance of the transistor on a wide range of charge carrier density and over several decades of electrolyte conductivity. We show that despite an exceptionally high capacitive coupling at the carbon-EMI-TFSI interface, the ionic and electronic transport pathways are decoupled at the micrometric scale, in agreement with predicted lengthscales involved in the electronic-ionic interfacial transport.

Indexed as

grapheneionic liquidliquid–solid interfaces

Identifiers

PMID40273106
PMCPMC12054819

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.