6-(4-Pyridyl)Azulene Derivatives as Hole Transport Materials for Perovskite Solar Cells.

Azulene has been attracting much attention as a charge transfer material in organic electronics due to its inherent large dipole moment and small band gap, but its application in perovskite solar cells (PSCs) is very limited. Herein, azulene was applied as the core acceptor for hole transport materials (HTMs), and two molecules named Azu-Py-DF and Azu-Py-OMeTPA were designed and synthesized, in which 4-pyridyl was introduced on the 6-position of the 1,3-substituted azulene core to adjust energy levels. The different spatial orientations of pyridine and the azulene core improve the solubility and reduce the crystallinity of the material, which is conducive to creating a thin film morphology. Azu-Py-OMeTPA exhibited good hole and electron mobility compared with standard Spiro-OMeTAD. Applied as an HTM in PSCs, the Azu-Py-OMeTPA-based device achieved a power conversion efficiency (PCE) of 18.10%, which is higher than that of the 6-position unsubstituted counterpart. Nevertheless, the anticipated passivation effect of the 4-pyridyl group was diminished due to the electron-deficient nature of azulene's seven-membered ring. These results demonstrate that optimizing the structure of azulene-based HTMs can significantly alter molecular spatial structure, film formation properties, electron delocalization characteristics and charge transport, and can lead to improved device performance, providing insights for the future design of novel HTMs.