Is Carbon Heteroatom Doping the Key to Active and Stable Carbon Supported Cobalt Fischer-Tropsch Catalysts?

Carbon supports are an interesting alternative to established oxidic catalyst supports for Co-based Fischer-Tropsch synthesis (FTS) catalysts as they allow high Co reducibility and do not suffer from the formation of Co/support compounds. To optimize Co-based carbon-supported FTS catalysts, significant research has focused on doping carbon supports with heteroatoms, aiming to enhance both catalytic activity and stability. While improvements in FTS performance have been reported for N-doped carbon supports, the exact effects of heteroatom doping are still poorly understood, largely due to difficulties in directly comparing Co FTS catalysts supported on doped versus nondoped carbon materials. In this study, we synthesized a series of highly comparable N-, S-, and P-doped carbon nanofiber (CNF) model supports, which were combined with size-controlled, colloidal Co nanoparticles to create well-defined model FTS catalysts. Comprehensive characterization of these catalysts using in situ X-ray absorption spectroscopy (XAS), in situ X-ray diffraction (XRD), and in situ magnetometry revealed that the presence of dopants significantly altered the structure and properties of the catalytically active Co