Evidence map›Paper›PMID 40270211›Full record

ArticleSmall (Weinheim an der Bergstrasse, Germany)2025

Revealing the Role of Spacer Length and Methoxy Substitution of Dipodal Indolocarbazole-based SAMs on the Performance of Inverted Perovskite Solar Cells.

José Manuel Ramón, José G Sánchez, Miriam Más-Montoya, Wenhui Li, Eugenia Martínez-Ferrero, Emilio Palomares, David Curiel

Abstract read
In one paragraph

Article in Small (Weinheim an der Bergstrasse, Germany), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

  1. Review
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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

José Manuel RamónDepartment of Organic Chemistry - Faculty of Chemistry, University of Murcia, Murcia, 30100, Spain.ORCID https://orcid.org/0009-0003-5011-660X
José G SánchezInstitute of Chemical Research of Catalonia (ICIQ-iCERCA-BIST), Avda. Països Catalans, 16, Tarragona, E-43007, Spain.ORCID https://orcid.org/0000-0002-2755-8878
Miriam Más-MontoyaDepartment of Organic Chemistry - Faculty of Chemistry, University of Murcia, Murcia, 30100, Spain.ORCID https://orcid.org/0000-0001-7161-6804
Wenhui LiInstitute of Chemical Research of Catalonia (ICIQ-iCERCA-BIST), Avda. Països Catalans, 16, Tarragona, E-43007, Spain.ORCID https://orcid.org/0000-0001-7655-8033
Eugenia Martínez-FerreroInstitute of Chemical Research of Catalonia (ICIQ-iCERCA-BIST), Avda. Països Catalans, 16, Tarragona, E-43007, Spain.ORCID https://orcid.org/0000-0001-7558-0271
Emilio PalomaresInstitute of Chemical Research of Catalonia (ICIQ-iCERCA-BIST), Avda. Països Catalans, 16, Tarragona, E-43007, Spain.ORCID https://orcid.org/0000-0002-5092-9227
David CurielDepartment of Organic Chemistry - Faculty of Chemistry, University of Murcia, Murcia, 30100, Spain.ORCID https://orcid.org/0000-0002-6717-6305

Funding

AGAUR 2021SGR01261Fundación Séneca 22058/PI/22Ministry of Science and Innovation FPU22/02159Ministry of Science and Innovation PID2021-122734OB-I00Ministry of Science and Innovation PID2022-1380866NB-I00Ministry of Science and Innovation RED2022-134939-TMinistry of Science and Innovation SeveroOchoaGrantCEX2019-000925-S
6 · The paper itself

Abstract

The application of self-assembled molecules (SAMs) as selective charge transport layers in inverted perovskite solar cells (iPSCs) has attracted significant interest because of their ability to provide high-efficiency and stable devices. In this work, four dipodal SAMs are reported based on π-expanded indolo[2,3-a]carbazole, incorporated as hole-selective contacts in iPSCs. The presence of methoxy substituents and the spacer length in SAMs are modified to assess their influence on the device performance. For that, the ITO/SAM and ITO/SAM/PSCs interfaces are characterized in detail, including theoretical studies and analysis of the complete device performance. These results demonstrate the multifactorial effect that SAMs have on the growth of crystalline perovskite and the charge dynamics in the devices. The resulting iPSCs show power conversion efficiency (PCE) between 19.76% and 22.20% with fill factors exceeding 82% in all cases and good stability under continuous illumination. Notably, SAM combining unsubstituted indolocarbazole and longer pentyl spacer (5CPICZ) shows the highest PCE of 22.20%. In contrast, analogous SAMs with propyl spacers (3CPICZ) achiev a PCE of 22.01%. The experimental results reveal that the improved PCE reached with unsubstituted indolocarbazole SAMs is attributed to reduced charge recombination and longer carrier lifetime owing to effective perovskite surface passivation.

Indexed as

indolocarbazoleperovskite solar cellself‐assembled molecules

Identifiers

PMID40270211
PMCPMC12138858

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.