ArticleAngewandte Chemie (International ed. in English)2025
Scalable Main Group Mechanocatalytic CO
Article in Angewandte Chemie (International ed. in English), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
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4 citing papers in PubMed.
- Tailoring Edge Sites of B‑Doped g‑CPrecision chemistry · 2026Article
- Multifunctional metal-organic frameworks for direct photosynthesis of cyclic carbonates from gaseous olefins.Nature communications · 2026Article
- A Mechanochemical Kolbe-Schmitt Reaction: Catechol Carboxylation Provides Building Blocks for Renewable Plasticizers.Angewandte Chemie (International ed. in English) · 2026Article
- Scalable Main Group Mechanocatalytic COAngewandte Chemie (International ed. in English) · 2025Article
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7 authors.
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Abstract
Over the past two decades, main group elements have gained attention as promising substitutes for precious metals in catalytic processes. Additionally, mechanochemistry is emerging as a field with the potential to promote catalytic reactions under mild conditions. Herein, we report a scalable, main-group mechanocatalytic synthesis of cyclic carbonates from both solid and liquid epoxides, using CO₂ as a renewable feedstock under mild conditions with a gallium aminotrisphenolate catalyst. Unlike solution-based methods that generally require high temperatures and/or high CO₂ pressures, this mechanocatalytic process operates at just 1 bar and room temperature. The developed mechanochemical method affords the targeted compounds in high yields while also enabling efficient transformation of multi-terminal epoxides and avoiding the conversion losses typically observed in solution. Furthermore, this scalable method outperforms solution-based approaches across all green metrics, setting a new benchmark for environmentally friendly synthesis.
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