Evidence map›Paper›PMID 40269266›Full record

ArticleNature chemistry2025

Lanthanide-nickel molecular intermetallic complexes featuring a ligand-free Ni

Panfeng Chuai, Ziqi Hu, Yang-Rong Yao, Zhanxin Jiang, Aman Ullah, Ya Zhao, Weiren Cheng, Muqing Chen, Eugenio Coronado, Shangfeng Yang and 1 more

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Article in Nature chemistry, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

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3 · Its place in the literature

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4 · The record

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PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

11 authors.

Panfeng Chuai *National Laboratory for Molecular Sciences, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing, People's Republic of China.ORCID http://orcid.org/0009-0001-0579-2524
Ziqi Hu *National Laboratory for Molecular Sciences, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing, People's Republic of China. huziqi@ustc.edu.cn.ORCID http://orcid.org/0000-0003-1830-1584
Yang-Rong Yao *Key Laboratory of Precision and Intelligent Chemistry, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), Department of Materials Science and Engineering, University of Science and Technology of China, Hefei, China.ORCID http://orcid.org/0000-0003-3495-1691
Zhanxin JiangKey Laboratory of Precision and Intelligent Chemistry, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), Department of Materials Science and Engineering, University of Science and Technology of China, Hefei, China.
Aman UllahInstituto de Ciencia Molecular, Universidad de Valencia, Paterna, Spain.
Ya ZhaoNational Laboratory for Molecular Sciences, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing, People's Republic of China.
Weiren ChengKey Laboratory of Precision and Intelligent Chemistry, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), Department of Materials Science and Engineering, University of Science and Technology of China, Hefei, China.ORCID http://orcid.org/0000-0001-6938-6296
Muqing ChenKey Laboratory of Precision and Intelligent Chemistry, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), Department of Materials Science and Engineering, University of Science and Technology of China, Hefei, China.ORCID http://orcid.org/0000-0002-7111-1782
Eugenio CoronadoInstituto de Ciencia Molecular, Universidad de Valencia, Paterna, Spain. eugenio.coronado@uv.es.ORCID http://orcid.org/0000-0002-1848-8791
Shangfeng YangKey Laboratory of Precision and Intelligent Chemistry, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), Department of Materials Science and Engineering, University of Science and Technology of China, Hefei, China. sfyang@ustc.edu.cn.ORCID http://orcid.org/0000-0002-6931-9613
Zujin ShiNational Laboratory for Molecular Sciences, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing, People's Republic of China. zjshi@pku.edu.cn.ORCID http://orcid.org/0000-0003-0268-4584

Funding

National Natural Science Foundation of China (National Science Foundation of China) 22275002Natural Science Foundation of Anhui Province (Anhui Provincial Natural Science Foundation) 2308085MB33
6 · The paper itself

Abstract

Transition metals (TMs) typically exhibit rich redox chemistry and can be found in various oxidation states. In most cases, TMs are positively charged. Strong π-accepting ligands have been shown to stabilize molecular complexes with TMs in formal negative oxidation states. By contrast, organic-ligand-free TM anions remain rare, limited to intermetallic compounds based on third-row TMs such as gold or platinum. Here we report the synthesis of air-stable lanthanide-nickel molecular intermetallic complexes featuring a ligand-free Ni

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.