ArticleAngewandte Chemie (International ed. in English)2025
Light-Induced Disruption of 1D Wire-Like Arrays of Monoatomic Ag(I) Ions: Single-Crystal Reaction with Crystal Softening.
Article in Angewandte Chemie (International ed. in English), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
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Who cites it
4 citing papers in PubMed.
- Heat- and Light-Directed Cycloadditions Enable a Pericyclic Cascade Reaction From a Molecular Precursor.Angewandte Chemie (International ed. in English) · 2026Article
- Solid-State Dynamic Behavior of the Boron-Nitrogen Bond Enables Mechanophotocatalysis of a [2 + 2]-Photocycloaddition.JACS Au · 2026Article
- Photofracking-Assisted Enhancement of Solid-State Photochemical Reactivity: α-Azido-5-phenyl-2,4-dienoate Derivatives.Journal of the American Chemical Society · 2026Article
- Light-Induced Disruption of 1D Wire-Like Arrays of Monoatomic Ag(I) Ions: Single-Crystal Reaction with Crystal Softening.Angewandte Chemie (International ed. in English) · 2025Article
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Authors and funding
6 authors.
Funding
Abstract
The exploitation of noncovalent bonding in the solid state is attractive to generate one-dimensional (1D) wire-like assemblies of metals and uncover dynamic and physical properties of such intriguing structures. Herein, we describe a metal-organic crystal based on Ag(I) ions that assemble to be organized into 1D wire-like assemblies maintained by argentophilic interactions. UV-light irradiation of the crystal composed of the 1D structures results in a single-crystal-to-single-crystal (SCSC) photodimerization that transforms the 1D periodic metal arrays to isolated metal dimers. The structural reconfiguration creates small voids in the crystal and the resulting solids exhibit a substantial increase in softness up to 60%.
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