ArticleChemSusChem2025
Mechanochemical Aerobic Activation of Metallic Copper for the Synthesis of 1,4-Allenynes.
Article in ChemSusChem, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
2 citing papers in PubMed.
- Silent Partners in the Mill: Unveiling the Role of Additives in Mechanochemical Synthesis.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Review
- Mechanochemical Activation of NaHCOChemSusChem · 2025Article
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Authors and funding
7 authors.
Funding
Abstract
Mechanical activation of zero-valent metals is emerging as a new paradigm in sustainable synthesis, opening up a broad swath of chemical space under more practical conditions than solution-phase methods. Contrary to its neighboring elements in the periodic table, copper has been significantly overlooked in this domain, especially for CC bond formation. Herein, a mechanochemical method for synthesizing >25 previously unreported conjugated allenynes-a valuable scaffold in organic synthesis is presented-through copper-catalyzed homocoupling of propargylic esters. This approach utilizes ball milling to activate inexpensive zero-valent copper under solvent-minimized conditions, sourced from both powders and recycled waste materials, including wires and bolts, into catalytically active Cu
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Registered trials
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