ArticleJournal of the American Chemical Society2025
Cobalt-Catalyzed Syntheses of Esters and Carboxylic Acids from Alkenes Promoted by Light.
Article in Journal of the American Chemical Society, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
5 citing papers in PubMed.
- Cobalt-Catalyzed Cyclohydrocarbonylations: Syntheses of Saturated Heterocycles Promoted by Light.Journal of the American Chemical Society · 2026Article
- Cobalt-Catalyzed Highly Regioselective Alkoxycarbonylation of Olefins Driven by Light.Journal of the American Chemical Society · 2026Article
- Cobalt-Catalyzed Syntheses of Acrylamides and Succindiamides from Alkynes and Amines Promoted by Light.Journal of the American Chemical Society · 2026Article
- Ambient Hydrocarbonylation of Olefins Enabled by Visible-Light.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Shedding Light on Photochemical Activation and Catalytic Mechanism of Cobalt-Catalyzed Alkene Hydroaminocarbonylation.ACS catalysis · 2025Article
Corrections and comments
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Authors and funding
3 authors.
Funding
Abstract
Alkoxy- and hydroxycarbonylations of alkenes are widely useful transformations for the preparation of esters and carboxylic acids, respectively. Catalytic systems using earth-abundant, first-row metals hold significant promise in increasing the scope and sustainability of these processes, but general methods remain virtually undeveloped. Herein, we report alkene alkoxycarbonylations and hydroxycarbonylations catalyzed by unmodified, inexpensive cobalt carbonyl under mild conditions and under low pressure promoted by light. These reactions display a broad substrate scope with respect to the alkene and alcohol components, with alkoxycarbonylations proceeding efficiently with 1 equiv of both partners, enabling coupling of complex substrates. A successful alkoxycarbonylation was performed even in the absence of solvent, displaying a remarkably low
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Registered trials
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