Evidence map›Paper›PMID 40247670›Full record

ArticleChemistry (Weinheim an der Bergstrasse, Germany)2025

From Donor-Acceptor Ligands to Smart Coordination Polymers: Cyanothiazole-Cu(I) Complexes for Multifunctional Electronic Devices.

Karolina Gutmańska, Agnieszka Podborska, Tomasz Mazur, Andrzej Sławek, Ramesh Sivasamy, Alexey Maximenko, Łukasz Orzeł, Janusz Oszajca, Grażyna Stochel, Amarjith V Dev and 3 more

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

13 authors.

Karolina GutmańskaChemical Faculty, Department of Inorganic Chemistry, Gdansk University of Technology, Narutowicza 11/12, Gdańsk, 80-233, Poland.
Agnieszka PodborskaAcademic Centre of Materials and Technology, AGH University of Krakow, Mickiewicza 30, Kraków, 30-059, Poland.ORCID https://orcid.org/0000-0002-1233-7300
Tomasz MazurAcademic Centre of Materials and Technology, AGH University of Krakow, Mickiewicza 30, Kraków, 30-059, Poland.ORCID https://orcid.org/0000-0003-4012-6778
Andrzej SławekAcademic Centre of Materials and Technology, AGH University of Krakow, Mickiewicza 30, Kraków, 30-059, Poland.ORCID https://orcid.org/0000-0002-1846-6883
Ramesh SivasamyAcademic Centre of Materials and Technology, AGH University of Krakow, Mickiewicza 30, Kraków, 30-059, Poland.ORCID https://orcid.org/0000-0002-4048-7648
Alexey MaximenkoNational Synchrotron Radiation Centre SOLARIS, Jagiellonian University, Czerwone Maki 98, Kraków, 30‑392, Poland.ORCID https://orcid.org/0000-0003-2660-8105
Łukasz OrzełFaculty of Chemistry, Jagiellonian University in Krakow, Gronostajowa 2, Kraków, 30-387, Poland.ORCID https://orcid.org/0000-0002-6943-7441
Janusz OszajcaFaculty of Chemistry, Jagiellonian University in Krakow, Gronostajowa 2, Kraków, 30-387, Poland.ORCID https://orcid.org/0000-0001-9349-7156
Grażyna StochelFaculty of Chemistry, Jagiellonian University in Krakow, Gronostajowa 2, Kraków, 30-387, Poland.ORCID https://orcid.org/0000-0002-9502-6371
Amarjith V DevChemical Sciences and Technology Division, CSIR-National Institute for Interdisciplinary Science and Technology (NIIST), Thiruvananthapuram, 695 019, India.
Chakkooth VijayakumarChemical Sciences and Technology Division, CSIR-National Institute for Interdisciplinary Science and Technology (NIIST), Thiruvananthapuram, 695 019, India.
Konrad SzaciłowskiAcademic Centre of Materials and Technology, AGH University of Krakow, Mickiewicza 30, Kraków, 30-059, Poland.ORCID https://orcid.org/0000-0002-1596-9856
Anna DołęgaChemical Faculty, Department of Inorganic Chemistry, Gdansk University of Technology, Narutowicza 11/12, Gdańsk, 80-233, Poland.ORCID https://orcid.org/0000-0003-0509-2285

Funding

Horizon 2020 952148-SylindaNarodowe Centrum Nauki 2022/47/B/ST4/00728
6 · The paper itself

Abstract

Cyanothiazoles, small and quite overlooked molecules, possess remarkable optical properties that can be fine-tuned through coordination with transition metals. In this study, we investigate a promising application of cyanothiazoles, where their combination with copper(I) iodide forms a new class of complexes exhibiting outstanding optical properties. X-ray crystallography of copper(I) iodide complexes with isomeric cyanothiazoles revealed key structural features, such as π─π stacking, hydrogen bonding, and rare halogen⋅⋅⋅chalcogen I⋅⋅⋅S interactions, enhancing stability and reactivity. Advanced spectroscopy and computational modeling allowed precise identification of spectral signatures in Fourier-transform infrared (FTIR), nuclear magnetic resonance (NMR), and ultraviolet-visible (UV-Vis) spectra. Fluorescence studies, along with X-ray absorption near edge structure (XANES) synchrotron analyses, highlighted their unique thermal and electronic properties, providing a solid foundation for further research in the field.

Indexed as

copper(I) iodidecyanothiazolesfluorescence spectroscopyX‐ray absorption spectroscopyX‐ray diffraction

Identifiers

PMID40247670
PMCPMC12133625

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.