ArticleNature communications2025
Electronic band structure engineering of π-d conjugated metal-organic framework for sodium organic batteries.
Article in Nature communications, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
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Who cites it
4 citing papers in PubMed.
- Construction of Interlayer 2D Conductive Channels in a TiChemistry, an Asian journal · 2026Article
- Tetraphenylborate-based anionic metal-organic framework as an efficient single-ion conductor for solid-state sodium batteries.Chemical science · 2026Article
- Multi-electron nitrobenzothiadiazole sp-conjugated-alkynyl covalent organic frameworks for ammonium-ion batteries.Nature communications · 2026Article
- Low-strain metal-organic framework negative electrode for stable all-solid-state batteries.Nature communications · 2025Article
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Authors and funding
6 authors.
Funding
Abstract
Two-dimensional conjugated metal organic frameworks (2D c-MOFs) hold significant promise as electrode materials for alkali metal ion batteries while their electrochemical properties still lack reasonable and effective regulation. Here, two representative 2D c-MOFs (M-HHTQ/M-HHTP, M=Cu or Ni) as positive electrodes are used as models to explore the basic/microscopic principles of their complex storage mechanism in sodium ion batteries (SIBs). It is demonstrated that the energy storage mechanism of 2D c-MOFs is determined by the interaction between coordination covalent bonds and organic linkers. Theoretical calculations and experiment results have jointly demonstrated that the redox potential and theoretical capacity can be regulated based on the valence of M-O bond and the utilization of anions and cations, respectively. As a result, Cu-HHTQ achieves a high discharge voltage at 2.55 V (vs. Na
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Registered trials
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