ArticleAngewandte Chemie (International ed. in English)2025
Photoelectrochemical Iron(III) Catalysis for Late-Stage C─H Fluoroalkylations.
Article in Angewandte Chemie (International ed. in English), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
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Who cites it
7 citing papers in PubMed.
- Combining Ag(II) and Ag(I) Reactivity Enables Electrophotochemical Acyl Fluoride Installation on (Hetero)Arenes.Journal of the American Chemical Society · 2026Article
- Electrophotochemical Decarboxylative C-H Fluoroalkylation via a FeACS catalysis · 2026Article
- Dual-role iron species in photoelectrocatalytic radical trifluoromethylation with trifluoroacetates.Nature communications · 2026Article
- Dual transition metal electrocatalysis for difluoromethylation of Aryl halides using potassium difluoroacetate.Nature communications · 2025Article
- LMCT-Driven Iron Photocatalysis: Mechanistic Insights and Synthetic Applications.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Review
- Ligand-to-Metal Charge Transfer of Ag(II) CFAngewandte Chemie (International ed. in English) · 2025Article
- Photoelectrochemical Iron(III) Catalysis for Late-Stage C─H Fluoroalkylations.Angewandte Chemie (International ed. in English) · 2025Article
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Authors and funding
9 authors.
Funding
Abstract
Chemo- and site-selective functionalization of complex molecules poses a fundamental challenge. Herein, we introduce a resource-economic photoelectrocatalysis strategy to enable versatile direct fluoroalkylations catalyzed by Earth-abundant iron and paired with the hydrogen evolution reaction (HER). Notably, the devised approach proved amenable to versatile late-stage C─H fluoroalkylations of bio-relevant heterocycles, such as xanthines, nucleobases, and nucleosides. Mechanistic studies supported a ligand-to-metal charge transfer-induced formation of the fluoroalkyl radical.
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Registered trials
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