Evidence map›Paper›PMID 40219223›Full record

ArticlePolymers2025

Exceptionally High-Temperature-Resistant Kapton-Type Polyimides with

Peng Xiao, Xiaojie He, Qinghua Lu

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Polymers, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Review
  2. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

3 authors.

Peng XiaoInstitute of Micro/Nano Materials and Devices, Ningbo University of Technology, Ningbo 315211, China.ORCID 0009-0008-0318-6249
Xiaojie HeSchool of Chemical Science and Technology, Tongji University, Siping Road No. 1239, Shanghai 200092, China.
Qinghua LuState Key Laboratory of Synergistic Chem-Bio Synthesis, School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Dongchuan Road No. 800, Shanghai 200240, China.

Funding

National Natural Science Foundation of China 51733007National Natural Science Foundation of China 52233016National Natural Science Foundation of China 52350337National Natural Science Foundation of China 52403010
6 · The paper itself

Abstract

Polyimides (PIs), recognized for their exceptional thermal stability, are extensively employed in advanced applications, including aerospace, flexible displays, flexible solar cells, flame-retardant materials, and high-temperature filtration materials. However, with the continuous advancements in science and technology, the demand for improved thermal performance of PIs in these application areas has increased significantly. In this study, four spirobis(indene)-bis(benzoxazole) diamine monomers (5a, 5aa, 5b and 5bb) were designed and synthesized. These monomers were copolymerized with pyromellitic dianhydride (PMDA) and 4,4-diaminodiphenylmethane (ODA) to develop Kapton-type PIs. By varying the copolymerization molar ratios of the different diamines, a series of novel ultrahigh-temperature-resistant PI films were successfully prepared, and it was found that incorporating a highly rigid and twisted spirobis(indene)-bis(benzoxazole) structure into the PI matrix enhances the rigidity of the polymer chains and restricts their mobility, thereby significantly improving the thermal performance of the PI films. When 5a and ODA were copolymerized at molar ratios of 1:9 and 4:6, the glass transition temperature (

Indexed as

good mechanical propertiesKapton-type polyimidesmolecular dynamics simulationsspirobis(indene)-bis(benzoxazole)ultra-high Tg

Identifiers

PMID40219223
PMCPMC11991488

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.