ArticleNature chemistry2025
Valence-delocalized trithorium nanocluster superatoms with open-shell exalted diamagnetism.
Article in Nature chemistry, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
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Who cites it
2 citing papers in PubMed.
- All-metal aromaticity of cyclo-BiNature chemistry · 2026Article
- Field-induced non-linear magnetic responses of all-metal Jellium σ-aromats.Nature communications · 2026Article
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Authors and funding
10 authors.
Funding
Abstract
Quantum-confined nanoclusters can be described by the jellium model, which emphasizes closed-shell electron configurations, but an open-shell variation with jellium aromaticity has been proposed. Such clusters are termed superatoms because they behave like an atom, and they exhibit unusual properties. Superatoms feature metal-metal bonding; hence, since their discovery 40 years ago, superatoms have exclusively involved main group or transition metals, with actinides only considered computationally as dopants owing to actinide-actinide bonding being exceedingly rare. Here we report trithorium nanoclusters exhibiting three-centre-one-electron actinide-actinide bonding. Experimental and computational analysis demonstrates Robin-Day Class III 6d-orbital valence delocalization in these clusters. These S = 1/2 clusters are paramagnetic, but in external applied magnetic fields they exhibit exalted diamagnetism, evidencing actinide open-shell jellium aromaticity superatom character. Exalted diamagnetism is not normally associated with a single unpaired electron, but with a 1S
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