ArticleChemical science2025
Redox-active polymer-grafted particles as redox mediators for enhanced charge transport in solution-state electrochemical systems.
Article in Chemical science, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
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Who cites it
4 citing papers in PubMed.
- Deciphering Concentration and Backbone Identity Effects on the Redox Properties of Phthalimide-Based Polymers.Chemistry of materials : a publication of the American Chemical Society · 2026Article
- Radical Polyesters: Connecting Spacer Structure to Bulk Electrical Conductivity.ACS macro letters · 2026Article
- Revealing the Effect of Pendant Identity on the Electrochemistry of Non-Conjugated Redox Active Polymers.ChemSusChem · 2025Article
- Polycondensation as a Universal Method for Preparing High-Density Single-Atom Catalyst Libraries.Advanced materials (Deerfield Beach, Fla.) · 2025Article
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Authors and funding
5 authors.
Funding
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Abstract
Efficient charge transport pathways in solutions of redox-active polymers are essential for advancing next-generation energy storage systems. Herein, we report the grafting of (2,2,6,6-tetramethylpiperidin-1-yl)oxyl (TEMPO) and poly(2,2,6,6-tetramethyl-1-piperidinyloxy-4-yl methacrylate) (PTMA) polymer brushes onto silica particles with different molecular weights and grafting densities, and the impact of these composite particles in solutions of PTMA. The polymer-grafted particles are characterized using Fourier-transform infrared (FTIR) spectroscopy, X-ray photoelectron spectroscopy (XPS), electron paramagnetic resonance (EPR) spectroscopy, field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), and dynamic light scattering (DLS) techniques. The grafted polymers have molecular weights of 2.5 kDa and 5.0 kDa, with corresponding grafting densities of 0.688 and 0.378 chains nm
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Registered trials
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