Evidence map›Paper›PMID 40212706›Full record

ArticleSmall science2022

Demystifying Activity Origin of M-N-C Single-Atomic Mediators Toward Expedited Rate-Determining Step in Li-S Electrochemistry.

Jia Jin, Zhongti Sun, Tianran Yan, Zixiong Shi, Meiyu Wang, Ting Huang, Yifan Ding, Jingsheng Cai, Peng Wang, Liang Zhang and 1 more

Abstract read
In one paragraph

Article in Small science, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

  1. tNature communications · 2025
    Article
  2. Review
  3. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

11 authors.

Jia JinCollege of Energy, Soochow Institute for Energy and Materials InnovationS (SIEMIS) Light Industry Institute of Electrochemical Power Sources Jiangsu Provincial Key Laboratory for Advanced Carbon Materials and Wearable Energy Technologies Soochow University Suzhou 215006 P. R. China.
Zhongti SunSchool of Materials Science and Engineering Jiangsu University Zhenjiang 212013 P. R. China.
Tianran YanInstitute of Functional Nano & Soft Materials (FUNSOM) Jiangsu Provincial Key Laboratory for Carbon-Based Functional Materials and Devices Soochow University Suzhou 215006 P. R. China.
Zixiong ShiCollege of Energy, Soochow Institute for Energy and Materials InnovationS (SIEMIS) Light Industry Institute of Electrochemical Power Sources Jiangsu Provincial Key Laboratory for Advanced Carbon Materials and Wearable Energy Technologies Soochow University Suzhou 215006 P. R. China.
Meiyu WangCollege of Engineering and Applied Sciences and Collaborative Innovation Center of Advanced Microstructures National Laboratory of Solid-State Microstructures Jiangsu Key Laboratory of Artificial Functional Materials Nanjing University Nanjing 210093 P. R. China.
Ting HuangCollege of Energy, Soochow Institute for Energy and Materials InnovationS (SIEMIS) Light Industry Institute of Electrochemical Power Sources Jiangsu Provincial Key Laboratory for Advanced Carbon Materials and Wearable Energy Technologies Soochow University Suzhou 215006 P. R. China.
Yifan DingCollege of Energy, Soochow Institute for Energy and Materials InnovationS (SIEMIS) Light Industry Institute of Electrochemical Power Sources Jiangsu Provincial Key Laboratory for Advanced Carbon Materials and Wearable Energy Technologies Soochow University Suzhou 215006 P. R. China.
Jingsheng CaiCollege of Energy, Soochow Institute for Energy and Materials InnovationS (SIEMIS) Light Industry Institute of Electrochemical Power Sources Jiangsu Provincial Key Laboratory for Advanced Carbon Materials and Wearable Energy Technologies Soochow University Suzhou 215006 P. R. China.
Peng WangCollege of Engineering and Applied Sciences and Collaborative Innovation Center of Advanced Microstructures National Laboratory of Solid-State Microstructures Jiangsu Key Laboratory of Artificial Functional Materials Nanjing University Nanjing 210093 P. R. China.
Liang ZhangInstitute of Functional Nano & Soft Materials (FUNSOM) Jiangsu Provincial Key Laboratory for Carbon-Based Functional Materials and Devices Soochow University Suzhou 215006 P. R. China.
Jingyu SunCollege of Energy, Soochow Institute for Energy and Materials InnovationS (SIEMIS) Light Industry Institute of Electrochemical Power Sources Jiangsu Provincial Key Laboratory for Advanced Carbon Materials and Wearable Energy Technologies Soochow University Suzhou 215006 P. R. China.ORCID 0000-0002-9812-3046

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Sluggish sulfur reduction reaction (SRR) kinetics remains a formidable challenge in Li-S electrochemistry. In this sense, the rational design of single-atom species has become a burgeoning practice to expedite sulfur redox, where the underlying catalytic mechanism otherwise remains elusive. Herein, a class of metal single-atom modified porous carbon nanofiber films (MSA PCNFs, M = Fe, Co, or Ni), fabricated via a generic synthetic strategy, as mediators to boost SRR kinetics is reported. Throughout electrokinetic measurement and operando instrumental probing, NiSA PCNF is evidenced to harness the catalytic superiority toward the rate-determining step (i.e., liquid-solid conversion) of the SRR process. Density functional theory (DFT) simulations further reveal that the catalytic features of M-N-C moieties in catalyzing the Li

Indexed as

Li–S batteriesM–N–Crate-determining stepsingle-atomic mediatorsulfur reduction reaction

Identifiers

PMID40212706
PMCPMC11935855

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.