ArticleSmall science2024
Orientation-Driven Large Magnetic Hysteresis of Er(III) Cyclooctatetraenide-Based Single-Ion Magnets Adsorbed on Ag(100).
Article in Small science, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
The molecular self-assembly and the magnetic properties of two cyclooctatetraenide (COT)-based single-ion magnets (SIM) adsorbed on Ag(100) in the sub-monolayer (ML) range are reported. Our study combines scanning-tunneling microscopy, X-ray photoemission spectroscopy and polarized X-ray absorption spectroscopy to show that Cp*ErCOT (Cp* = 1,2,3,4,5-pentamethylcyclopentadienide anion) SIMs self-assemble as alternating compact parallel rows including standing-up and lying-down conformations, following the main crystallographic directions of the substrate. Conversely, K[Er(COT)
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