Evidence map›Paper›PMID 40208948›Full record

ArticleProceedings of the National Academy of Sciences of the United States of America2025

In situ generated hydrogen-bonding microenvironment in functionalized MOF nanosheets for enhanced CO

Ge Yang, Jiajia Huang, Weizhi Gu, Zhongyuan Lin, Qingyu Wang, Rong Kang, Jing-Yao Liu, Zhihu Sun, Xusheng Zheng, Long Jiao and 1 more

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Proceedings of the National Academy of Sciences of the United States of America, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

  1. Organometallic Frameworks for Efficient Electrocatalytic COAngewandte Chemie (International ed. in English) · 2026
    Article
  2. Review
  3. Photocatalytic Co-Reduction of COAngewandte Chemie (International ed. in English) · 2025
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

11 authors.

Ge Yang *Hefei National Research Center for Physical Sciences at the Microscale, Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, People's Republic of China.
Jiajia Huang *Hefei National Research Center for Physical Sciences at the Microscale, Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, People's Republic of China.ORCID 0000-0002-9498-0542
Weizhi GuKey Laboratory of Precision and Intelligent Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, People's Republic of China.
Zhongyuan LinHefei National Research Center for Physical Sciences at the Microscale, Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, People's Republic of China.
Qingyu WangNational Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei, Anhui 230029, People's Republic of China.
Rong KangHefei National Research Center for Physical Sciences at the Microscale, Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, People's Republic of China.
Jing-Yao LiuLaboratory of Theoretical and Computational Chemistry, Institute of Theoretical Chemistry, College of Chemistry, Jilin University, Changchun, Jilin 130023, People's Republic of China.
Zhihu SunNational Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei, Anhui 230029, People's Republic of China.ORCID 0000-0002-3898-969X
Xusheng ZhengNational Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei, Anhui 230029, People's Republic of China.ORCID 0000-0003-2559-6106
Long JiaoKey Laboratory of Precision and Intelligent Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, People's Republic of China.
Hai-Long JiangHefei National Research Center for Physical Sciences at the Microscale, Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, People's Republic of China.ORCID 0000-0002-2975-7977

Funding

Major Industrial Innovation Plan of Anhui Province AHZDCYCX-LSDT2023-04MOE | Fundamental Research Funds for the Central Universities (Fundamental Research Fund for the Central Universities) WK2060000040MOST | National Key Research and Development Program of China (NKPs) 2021YFA1500402MOST | National Natural Science Foundation of China (NSFC) 22222507 22375193MOST | National Natural Science Foundation of China (NSFC) 22331009 U22A20401Postdoctoral Fellowship Program of CPSF GZC20232532Strategic Priority Research Program of the Chinese Academy of Sciences XDB0450302 XDB0540000the University Synergy Innovation Program of Anhui Province GXXT-2022-006
6 · The paper itself

Abstract

The microenvironment around catalytic sites plays crucial roles in enzymatic catalysis while its precise control in heterogeneous catalysts remains challenging. Herein, the coordinatively unsaturated metal nodes of Hf-based metal-organic framework nanosheets are simultaneously codecorated with catalytically active Co(salen) units and adjacent pyridyl-substituted alkyl carboxylic acids via a post modification route. By varying pyridyl-substituted alkyl carboxylic acids, the spatial positioning of the N atom in pyridine group relative to adjacent Co(salen) can be precisely controlled. Notably, the 3-(pyridin-4-yl)propionic acid, with

Indexed as

CO2 reductionelectrocatalysishydrogen bondingmetal-organic frameworksmicroenvironment

Identifiers

PMID40208948
PMCPMC12012543

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.