ArticleNature communications2025
Alchemically-glazed plasmonic nanocavities using atomic layer metals: controllably synergizing catalysis and plasmonics.
Article in Nature communications, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
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Who cites it
6 citing papers in PubMed.
- Surface-Selective Molecular Binding and Replacement Selectivity in Plasmonic Nanocavities.The journal of physical chemistry letters · 2026Article
- Spatiotemporal Raman probing of molecular transport in sub-2-nm plasmonic quasi-2D nanochannels.Science advances · 2026Article
- Quantum Hydrodynamic Theory for Sub-Nanometer Gaps: Atomic Protrusions Govern Near-Field Enhancement and Tunneling Signatures.Materials (Basel, Switzerland) · 2026Article
- Tracking and Controlling Monolayer Water in Gold Nanogaps using Extreme Plasmonic Spectroscopy.Small (Weinheim an der Bergstrasse, Germany) · 2025Article
- Tracking Molecular Shear at Metal Surfaces Using Enhanced Lamb Wave Scattering in Plasmonic Nanocavities.Nano letters · 2025Article
- Mapping Atomic-Scale Metal-Molecule Interactions: Salient Feature Extraction through Autoencoding of Vibrational Spectroscopy Data.The journal of physical chemistry letters · 2023Article
Corrections and comments
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Authors and funding
6 authors.
Funding
Abstract
Plasmonic nanocavities offer exceptional confinement of light, making them effective for energy conversion applications. However, limitations with stability, materials, and chemical activity have impeded their practical implementation. Here we integrate ultrathin palladium (Pd) metal films from sub- to few- atomic monolayers inside plasmonic nanocavities using underpotential deposition. Despite the poor plasmonic properties of bulk Pd in the visible region, minimal loss in optical field enhancement is delivered along with Pd chemical enhancement, as confirmed by ab initio calculations. Such synergistic effects significantly enhance photocatalytic activity of the plasmonic nanocavities as well as photostability by suppressing surface atom migration. We show the atomic alchemical-glazing approach is general for a range of catalytic metals that bridge plasmonic and chemical catalysis, yielding broad applications in photocatalysis for optimal chemical transformation.
Identifiers
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Registered trials
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