ArticleAngewandte Chemie (International ed. in English)2025
Efficient Semitransparent Organic Solar Modules with Exceptional Diurnal Stability Through Asymmetric Interaction Induced by Symmetric Molecular Structure.
Article in Angewandte Chemie (International ed. in English), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
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6 citing papers in PubMed.
- Side-Chain Length Modulation in Thieno[3,2‑ACS omega · 2026Article
- Modulating Surface Potential and Electron/Hole Overlap of Singlet Excited State in Asymmetry End-Capped Dimeric Acceptors for Efficient and Stretchable Organic Solar Cells.Angewandte Chemie (International ed. in English) · 2026Article
- Rational Asymmetric Acceptor Engineering via Unidirectional Terminal π-Extension and Optimizing Alkyl Branching Sites Affords a Binary Photovoltaic Efficiency of 20.7% by Suppressed Nonradiative Energy Loss.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Self-Assembled Monolayer Anode Enables 7% Efficiency in Y6-Based Quasi-Homojunction Solar Cells With 4% Donor Contents.Small science · 2026Article
- 3D Conjugated Nonflat Biphenyl Side Chains: Their Exclusive Role in Inducing Negative Electrostatic Potential in Efficient Organic Solar Cells.Small (Weinheim an der Bergstrasse, Germany) · 2025Article
- Efficient Semitransparent Organic Solar Modules with Exceptional Diurnal Stability Through Asymmetric Interaction Induced by Symmetric Molecular Structure.Angewandte Chemie (International ed. in English) · 2025Article
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16 authors.
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Abstract
The symmetry-breaking design strategy of nonfullerene acceptor can improve the performance of semitransparent organic solar cells (ST-OSCs). However, no report exists on the "asymmetric molecular interaction" induced by symmetric molecular structure in nonfullerene acceptors. Herein, we showcase that 2D fluorophenyl outer groups in symmetric 4FY promote dipole-driven self-assembly through asymmetric molecular interactions, resulting in a tighter packed structure than Y6 with the same symmetric geometry. Such unique properties lead to high-performance layer-by-layer OSCs, accompanied by simultaneously reduced energy and recombination losses and improved charge-related characteristics. ST-OSCs based on PCE10-2F/4FY achieve notable power conversion efficiency (PCE) of 10.81%, average visible transmittance of 45.43%, and light utilization efficiency (LUE) of 4.91%. Moreover, exceptional diurnal cycling stability is observed in the ST-OSCs based on PCE10-2F/4FY with much prolonged T
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