Evidence map›Paper›PMID 40195436›Full record

ArticleNature chemistry2025

Praseodymium in the formal +5 oxidation state.

Andrew C Boggiano, Chad M Studvick, Sabyasachi Roy Chowdhury, Julie E Niklas, Haruko Tateyama, Hongwei Wu, Johannes E Leisen, Florian Kleemiss, Bess Vlaisavljevich, Ivan A Popov and 1 more

Abstract read
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Article in Nature chemistry, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 12 papers.

0numbers the graph read from it
0cells of the map it votes in
12citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

12 citing papers in PubMed.

  1. Article
  2. Article
  3. Review
  4. Article
  5. Article
  6. Article
  7. Single-Determinant Ground State in CeInorganic chemistry · 2025
    Article
  8. Article
  9. A high-five for praseodymium.Nature chemistry · 2025
    Article
  10. Four-Centre, Multielectron Bonding in Rare-Earth Germole Sandwich Complexes.Angewandte Chemie (International ed. in English) · 2025
    Article
  11. Article
  12. UInorganic chemistry · 2025
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

11 authors.

Andrew C BoggianoSchool of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, GA, USA.ORCID http://orcid.org/0000-0002-5444-485X
Chad M StudvickDepartment of Chemistry, The University of Akron, Akron, OH, USA.ORCID http://orcid.org/0000-0002-4249-776X
Sabyasachi Roy ChowdhuryDepartment of Chemistry, The University of South Dakota, Vermillion, SD, USA.ORCID http://orcid.org/0000-0001-9000-8476
Julie E NiklasSchool of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, GA, USA.
Haruko TateyamaSchool of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, GA, USA.ORCID http://orcid.org/0000-0003-2382-9420
Hongwei WuSchool of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, GA, USA.ORCID http://orcid.org/0000-0002-8687-3843
Johannes E LeisenSchool of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, GA, USA.ORCID http://orcid.org/0000-0003-0474-670X
Florian KleemissInstitut für Anorganische Chemie, RWTH Aachen University, Aachen, Germany.ORCID http://orcid.org/0000-0002-3631-1535
Bess VlaisavljevichDepartment of Chemistry, The University of South Dakota, Vermillion, SD, USA. bess-vlaisavljevich@uiowa.edu.ORCID http://orcid.org/0000-0001-6065-0732
Ivan A PopovDepartment of Chemistry, Washington State University, Pullman, WA, USA. ivan.popov@wsu.edu.ORCID http://orcid.org/0000-0003-2663-3685
Henry S La PierreSchool of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, GA, USA. hsl@gatech.edu.ORCID http://orcid.org/0000-0002-0895-0655

Funding

National Science Foundation (NSF) OAC1626516U.S. Department of Energy (DOE) DESC0023022
6 · The paper itself

Abstract

Praseodymium in the +5 oxidation state is a long-sought connection between lanthanide, early-transition and actinide metal redox chemistries. Unique among the lanthanide series, evidence for molecular pentavalent praseodymium species has been observed in the gas phase and noble gas matrix isolation conditions. Here we report the low-temperature synthesis and characterization of a molecular praseodymium complex in the formal +5 oxidation state, [Pr

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.