Evidence map›Paper›PMID 40192628›Full record

ArticleChemistry (Weinheim an der Bergstrasse, Germany)2025

A Lewis Base-Free Trialumane: Enhanced Electrophilicity Based on Consecutive Vacant Orbitals Over Three Aluminum Atoms.

Ryotaro Yamanashi, Chaoqi Chen, Takumi Moriyama, Satoshi Muratsugu, Mizuki Tada, Taisuke Ozaki, Makoto Yamashita

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

  1. An FeInorganic chemistry · 2026
    Article
  2. A neutral cyclic aluminium (I) trimer.Nature communications · 2026
    Article
  3. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Ryotaro YamanashiDepartment of Molecular and Macromolecular Chemistry, Graduate School of Engineering, Nagoya University, Tokai National Higher Education and Research System, Furo-cho, Chikusa-ku, Nagoya, Aichi, 464-8603, Japan.
Chaoqi ChenDepartment of Chemistry, Graduate School of Science, Nagoya University, Tokai National Higher Education and Research System, Furo-cho, Chikusa-ku, Nagoya, Aichi, 464-8602, Japan.
Takumi MoriyamaDepartment of Chemistry, Graduate School of Science, Nagoya University, Tokai National Higher Education and Research System, Furo-cho, Chikusa-ku, Nagoya, Aichi, 464-8602, Japan.
Satoshi MuratsuguDepartment of Chemistry, Graduate School of Science, Nagoya University, Tokai National Higher Education and Research System, Furo-cho, Chikusa-ku, Nagoya, Aichi, 464-8602, Japan.
Mizuki TadaDepartment of Chemistry, Graduate School of Science, Nagoya University, Tokai National Higher Education and Research System, Furo-cho, Chikusa-ku, Nagoya, Aichi, 464-8602, Japan.
Taisuke OzakiThe Institute for Solid State Physics, The University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba, 277-8581, Japan.
Makoto YamashitaDepartment of Chemistry, School of Science, Institute of Science Tokyo, 2-12-1 Ookayama, Meguro-ku, Tokyo, 152-8551, Japan.ORCID https://orcid.org/0000-0002-3665-5311

Funding

Graduate Program of Transformative Chem-Bio ResearchJapan Society for the Promotion of Science 22J23885Japan Society for the Promotion of Science 23K26666Japan Society for the Promotion of Science 24H00455
6 · The paper itself

Abstract

A Lewis base-free trialumane having a 2,4,6-triisopropylphenyl (Tip) substituent was synthesized by a reaction of alumanyl anion with TipAlBr

Indexed as

aluminumcatenationlewis acidityreductionvacant orbitals

Identifiers

PMID40192628
PMCPMC12089911

What OpenQuestion holds

Textmetadata
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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.