ArticleChemistry (Weinheim an der Bergstrasse, Germany)2025
Preassembly-Controlled Radical Recombination at Bismuth: Decarboxylative C─N Coupling with Sulfonamides.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
4 citing papers in PubMed.
- Unlocking Li/Mg-Based Photochemical Nitration Platforms for Anticancer Drug Discovery.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Fe(III)/Pyridine N-oxide LMCT Photocatalysis for Unactivated C(spACS catalysis · 2026Article
- Leveraging Divergent Ligand-to-Metal Charge-Transfer Excited State Pathways for Catalyst Control over Alkoxyl Radical Reactivity.Journal of the American Chemical Society · 2026Article
- Harnessing Photochemistry in Natural Product Synthesis: From Strategy to Applications.Journal of natural products · 2025Review
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Authors and funding
4 authors.
Funding
Abstract
Persistent transition metal radicals form the foundation for many metallaphotoredox protocols. Their ability to efficiently trap organic radicals and convert them into various coupling products has inspired the exploration of selective radical reactions even beyond the d-block. Radical processes involving bismuth hold great potential, but innovative strategies are required to control the reactivity of bismuth intermediates. Herein, we report preassembly as a powerful strategy to enforce a selective recombination of a bismuth(II) radical and an organic radical. As a result, an inner-sphere pathway is accessed, enabling the formation of C─N coupling products.
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Registered trials
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