When Pore Met Semi: Charting the Rise of Porous Metal Halide Semiconductors.

Ali Azmy, Alissa Brooke Anderson, Mina Bagherifard, Neelam Tariq, Kamal E S Nassar, Ioannis Spanopoulos

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Review in ACS organic & inorganic Au, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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5 · Who and what money

Authors and funding

6 authors.

Ali AzmyDepartment of Chemistry, University of South Florida, Tampa, Florida 33620, United States.

Alissa Brooke AndersonDepartment of Chemistry, University of South Florida, Tampa, Florida 33620, United States.

Mina BagherifardDepartment of Chemistry, University of South Florida, Tampa, Florida 33620, United States.

Neelam TariqDepartment of Chemistry, University of South Florida, Tampa, Florida 33620, United States.

Kamal E S NassarDepartment of Chemistry, University of South Florida, Tampa, Florida 33620, United States.

Ioannis SpanopoulosDepartment of Chemistry, University of South Florida, Tampa, Florida 33620, United States.ORCID https://orcid.org/0000-0003-0861-1407

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Metal halide semiconductors (MHS) are a versatile class of materials with fully customizable mechanical and optoelectronic properties that have proven to be prominent candidates in numerous impactful applications. Finding a way to generate porosity in MHS would bestow upon them an additional node in property engineering, thus allowing them to be utilized in uncharted technologies. Motivated by this promise, we developed a general strategy to render the MHS porous. We employed molecular cages as structure-directing agents and countercations, which fostered a new family of materials: porous metal halide semiconductors (PMHS). The presence of molecular cages gave rise to ultramicroporous structures imposed by the organic part cavities and a record water stability performance of 27 months so far. In this Perspective, we discuss the principles and promises of PMHS, which combine the merits of porous and electronic compounds.

Identifiers

PMID40190390

DOI10.1021/acsorginorgau.4c00093

PMCPMC11969274

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LicenceCC BY-NC-ND

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.