Evidence map›Paper›PMID 40185796›Full record

ArticleNature communications2025

Defying the oxidative-addition prerequisite in cross-coupling through artful single-atom catalysts.

Jiwei Shi, Gang Wang, Duanshuai Tian, Xiao Hai, Rongwei Meng, Yifan Xu, Yu Teng, Lu Ma, Shibo Xi, Youqing Yang and 16 more

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Nature communications, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

  1. Article
  2. Article
  3. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

26 authors.

Jiwei Shi *Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore, Singapore.ORCID http://orcid.org/0000-0003-3625-9324
Gang Wang *Department of Chemistry and Guangdong Provincial Key Laboratory of Catalysis, Southern University of Science and Technology, Shenzhen, 518055, Guangdong, China.ORCID http://orcid.org/0000-0001-6857-5415
Duanshuai Tian *Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore, Singapore.
Xiao HaiSchool of Materials Science and Engineering, Peking University, Beijing, P.R. China. xiaohai@pku.edu.cn.ORCID http://orcid.org/0000-0002-7631-9769
Rongwei Meng *Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore, Singapore.
Yifan XuSchool of Materials and Engineering, Nanyang Technological University, Singapore, Singapore.ORCID http://orcid.org/0000-0002-0153-7761
Yu TengDepartment of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore, Singapore.
Lu MaNational Synchrotron Light Source II Brookhaven National Lab Upton, Upton, NY, USA.
Shibo XiInstitute of Sustainability for Chemicals, Energy and Environment (ISCE2), Agency for Science, Technology and Research (A*STAR), 1 Pesek Road Jurong Island, Singapore, 627833, Republic of Singapore.ORCID http://orcid.org/0000-0002-8521-3237
Youqing YangDepartment of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore, Singapore.
Xin ZhouDepartment of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore, Singapore.ORCID http://orcid.org/0000-0002-6431-731X
Xingjie FuDepartment of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore, Singapore.
Hengyu LiDepartment of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore, Singapore.
Qilong CaiDepartment of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore, Singapore.
Peng HeDepartment of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore, Singapore.
Huihui LinDepartment of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore, Singapore.ORCID http://orcid.org/0000-0002-1971-3380
Jinxing ChenDepartment of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore, Singapore.
Jiali LiDepartment of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore, Singapore.ORCID http://orcid.org/0000-0001-8990-9998
Jinghan LiSchool of Environmental Science and Engineering, Suzhou University of Science and Technology, Suzhou, 215009, China.
Qian HeDepartment of Material Science and Engineering, College of Design and Engineering, National University of, Singapore, 9 Engineering Drive 1, EA #03-09, Singapore.ORCID http://orcid.org/0000-0003-4891-3581
Quan-Hong YangJoint School of National University of Singapore and Tianjin University, International Campus of Tianjin University, Binhai New City, Fuzhou, 350207, China.ORCID http://orcid.org/0000-0003-2882-3968
Jun LiDepartment of Chemistry and Guangdong Provincial Key Laboratory of Catalysis, Southern University of Science and Technology, Shenzhen, 518055, Guangdong, China.ORCID http://orcid.org/0000-0002-8456-3980
Dongshuang WuSchool of Materials and Engineering, Nanyang Technological University, Singapore, Singapore. dongshuang.wu@ntu.edu.sg.ORCID http://orcid.org/0000-0001-8512-8473
Yang-Gang WangDepartment of Chemistry and Guangdong Provincial Key Laboratory of Catalysis, Southern University of Science and Technology, Shenzhen, 518055, Guangdong, China. wangyg@sustech.edu.cn.ORCID http://orcid.org/0000-0002-0582-0855
Jie WuDepartment of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore, Singapore. chmjie@nus.edu.sg.ORCID http://orcid.org/0000-0002-9865-180X
Jiong LuDepartment of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore, Singapore. chmluj@nus.edu.sg.ORCID http://orcid.org/0000-0002-3690-8235

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Heterogeneous single-atom catalysts (SACs) have gained significant attention for their maximized atom utilization and well-defined active sites, but they often struggle with multi-stage organic cross-coupling reactions due to limited coordination space and reactivity. Here, we report an "anchoring-borrowing" strategy combined facet engineering to develop artful single-atom catalysts (ASACs) through anchoring foreign single atoms onto specific facets of the non-innocent reducible carriers. ASACs exhibit adaptive coordination, effectively bypassing the oxidative-addition prerequisite for bivalent elevation at a single metal site in both homogenous and heterogeneous cross-couplings. For example, Pd

Identifiers

PMID40185796
PMCPMC11971317

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.