ArticleScience advances2025
Experimental quantification of nuclear quantum effects on the hydrogen bond of liquid water.
Article in Science advances, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
What it found
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Who cites it
6 citing papers in PubMed.
- Visible light leaves evaporation and interfacial structure of neat water unchanged at the air-water interface.Proceedings of the National Academy of Sciences of the United States of America · 2026Article
- Nuclear quantum effects amplify autoionization-driven superionic behaviour in nanoconfined monolayer water.Chemical science · 2026Article
- Nuclear Quantum Effects on the Dynamics of Bulk Water and Supercooled Aqueous Solutions.The journal of physical chemistry letters · 2026Article
- Leveraging the kinetic isotope effect by compact H-bond motifs for electrochemical hydrogen isotope separation.Proceedings of the National Academy of Sciences of the United States of America · 2026Article
- Reevaluating Anomalous Electric Fields at the Air-Water Interface: A Surface-Specific Spectroscopic Survey.Journal of the American Chemical Society · 2025Article
- Structure and Nonlinear Spectra of the Basal Face of Hexagonal Ice: A Molecular Dynamics Study.Molecules (Basel, Switzerland) · 2025Article
Corrections and comments
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Authors and funding
4 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Nuclear quantum effects (NQEs) significantly influence material properties upon isotopic substitution, particularly with light atoms such as hydrogen. While water is rich in hydrogen, its hydrogen-bonded structure exhibits only moderate NQEs. Simulations ascribe this to competing zero-point energies (ZPEs): Intermolecular ZPEs stabilize hydrogen-bonds, while intramolecular ZPEs destabilize them. However, experimental validation has been lacking due to the difficulty in quantifying NQEs. The air/water interface provides an ideal platform to quantify NQEs in liquid water using surface-specific vibrational spectroscopy. By analyzing the excess/depletion of interfacial HOD, H
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Registered trials
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