Thermally Activated on-Surface Self-Metalation of Pd-Phthalocyanines.

Mattia Bassotti, Stefania Baronio, Luca Floreano, Luca Schio, Erik Vesselli, Alberto Verdini

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Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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Authors and funding

6 authors.

Mattia BassottiDepartment of Physics and Geology, University of Perugia, Via A. Pascoli, Perugia, 06123, Italy.ORCID https://orcid.org/0000-0002-5866-0883

Stefania BaronioDepartment of Physics, University of Trieste, Via Valerio 2, Trieste, 34127, Italy.

Luca FloreanoCNR - Instituto Officina dei Materiali, Area Science Park, Trieste, 34149, Italy.

Luca SchioCNR - Instituto Officina dei Materiali, Area Science Park, Trieste, 34149, Italy.

Erik VesselliDepartment of Physics, University of Trieste, Via Valerio 2, Trieste, 34127, Italy.

Alberto VerdiniCNR-IOM, Perugia Unit, c/o Department of Physics and Geology, University of Perugia, Via A. Pascoli, Perugia, 06123, Italy.ORCID https://orcid.org/0000-0001-8880-2080

Funding

MUR Progetti di Ricerca di Rilevante Interesse Nazionale (PRIN) 2017KFY7XF

6 · The paper itself

Abstract

Phthalocyanines (Pcs) are essential organic molecules with wide-ranging applications in fields such as catalysis and optoelectronics, owing to their stable aromatic structure and exceptional thermal stability. Equally important is their versatility, which can be achieved by modifying the central metal atom. In this context, metalation-the process by which a central metal atom is incorporated into the macrocycle-plays a critical role in tailoring both the electronic and structural properties of Pcs. In this work, we investigate the thermally activated on-surface synthesis of palladium phthalocyanine (PdPc) by depositing metal-free phthalocyanine (

Indexed as

metalationphotoelectron spectroscopyphthalocyaninessurface chemistryx‐ray absorption spectroscopy

Identifiers

PMID40179056

DOI10.1002/chem.202500944

PMCPMC12089924

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