Evidence map›Paper›PMID 40177313›Full record

ArticleChemical science2025

Umpolung of a covalent organic framework for high-performance cathodic sodium ion storage.

Fangyuan Kang, Yuchan Zhang, Zihao Chen, Zhaowen Bai, Qianfeng Gu, Jinglun Yang, Qi Liu, Yang Ren, Chun-Sing Lee, Qichun Zhang

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Chemical science, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

10 authors.

Fangyuan KangDepartment of Materials Science and Engineering, City University of Hong Kong Tat Chee Avenue 83 Kowloon Hong Kong SAR 999077 P. R. China qiczhang@cityu.edu.hk.ORCID https://orcid.org/0000-0002-4279-2929
Yuchan ZhangDepartment of Materials Science and Engineering, City University of Hong Kong Tat Chee Avenue 83 Kowloon Hong Kong SAR 999077 P. R. China qiczhang@cityu.edu.hk.
Zihao ChenDepartment of Materials Science and Engineering, City University of Hong Kong Tat Chee Avenue 83 Kowloon Hong Kong SAR 999077 P. R. China qiczhang@cityu.edu.hk.
Zhaowen BaiDepartment of Physics, City University of Hong Kong Tat Chee Avenue 83 Kowloon Hong Kong SAR 999077 P. R. China.
Qianfeng GuDepartment of Materials Science and Engineering, City University of Hong Kong Tat Chee Avenue 83 Kowloon Hong Kong SAR 999077 P. R. China qiczhang@cityu.edu.hk.ORCID https://orcid.org/0000-0003-4581-9565
Jinglun YangDepartment of Materials Science and Engineering, City University of Hong Kong Tat Chee Avenue 83 Kowloon Hong Kong SAR 999077 P. R. China qiczhang@cityu.edu.hk.
Qi LiuDepartment of Physics, City University of Hong Kong Tat Chee Avenue 83 Kowloon Hong Kong SAR 999077 P. R. China.ORCID https://orcid.org/0000-0003-4879-1537
Yang RenDepartment of Physics, City University of Hong Kong Tat Chee Avenue 83 Kowloon Hong Kong SAR 999077 P. R. China.
Chun-Sing LeeDepartment of Chemistry, Center of Super-Diamond and Advanced Films (COSDAF), Hong Kong Institute of Clean Energy (HKICE), City University of Hong Kong Hong Kong SAR 999077 P. R. China apcslee@cityu.edu.hk.ORCID https://orcid.org/0000-0001-6557-453X
Qichun ZhangDepartment of Materials Science and Engineering, City University of Hong Kong Tat Chee Avenue 83 Kowloon Hong Kong SAR 999077 P. R. China qiczhang@cityu.edu.hk.ORCID https://orcid.org/0000-0003-1854-8659

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The rational design of electrode materials to modify their intrinsic electronic states effectively enhances the performance of rechargeable batteries. Herein, an umpolung strategy is implemented in preparing a polyimide-linked COF (CityU-47) through a polar inversion of the typical p-type triphenylamine (TPA) with a multi-carbonyl-contained n-type azatriangulenetrione (ATTO). This strategy can substantially decrease the energy level of the lowest unoccupied molecular orbital (LUMO), thereby increasing the potential for operation as a cathode material. Alongside increased specific capacity, an improved overall performance in sodium-ion batteries (SIBs) is achieved. Specifically, CityU-47 provides a high capacity of 286.31 mA h g

Identifiers

PMID40177313
PMCPMC11960781

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.