ArticleJournal of the American Chemical Society2025
Motivation on Intramolecular Through-Space Charge Transfer for the Realization of Thermally Activated Delayed Fluorescence (TADF)-Thermally Stimulated Delayed Phosphorescence (TSDP) in C^C^N Gold(III) Complexes and Their Applications in Organic Light-Emitting Devices.
Article in Journal of the American Chemical Society, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
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Who cites it
4 citing papers in PubMed.
- Highly efficient dual-channel doublet emission in lanthanide cerium(III) complex.Light, science & applications · 2026Article
- Frontier Advances of Terpyridine-Zn(II) Complexes: From Molecular Design to Smart Functional Materials.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Review
- Cost-Effective Multi-Channel MolOrbImage for Machine-Learned Excited-State Properties of Practical Photofunctional Materials.Journal of chemical theory and computation · 2026Article
- Linker-Dependent Variation in the Photophysical Properties of Dinuclear 2-Phenylpyridinato(salicylaldiminato)platinum(II) Complexes Featuring NDI Units.Molecules (Basel, Switzerland) · 2025Article
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Authors and funding
9 authors.
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Abstract
Thermally activated delayed fluorescence (TADF) and the very recently established thermally stimulated delayed phosphorescence (TSDP) are two promising approaches for enhancing the performance of organic light-emitting devices (OLEDs). Here, we have developed a new class of through-space charge transfer (TSCT) carbazolylgold(III) C^C^N complexes with unique TADF-TSDP properties by introducing a rigid arylamine on the carbazolyl auxiliary ligand. The highly twisted conformation between the C^C^N and carbazolyl ligands induces strong through-bond ligand-to-ligand charge transfer (TB-LLCT) character in their lowest singlet and triplet excited states, with small singlet-triplet energy gaps for efficient TADF. Moreover, the close spatial proximity between the cyclometalating ligand and the lateral arylamine enables appreciable intramolecular through-space electronic coupling that allows the generation of relatively low-lying triplet through-space ligand-to-ligand charge transfer (
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Registered trials
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