Evidence map›Paper›PMID 40144500›Full record

ReviewChemical science2025

Structural evolution of metal single-atoms and clusters in catalysis: Which are the active sites under operative conditions?

Shiyan Wang, Chaopeng Liu, Weiyao Hao, Yanling Zhuang, Jianmei Chen, Xianjun Zhu, Longlu Wang, Xianghong Niu, Jianjun Mao, Dongwei Ma and 1 more

Abstract readReview
In one paragraph

Review in Chemical science, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.

0numbers the graph read from it
0cells of the map it votes in
8citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

8 citing papers in PubMed.

  1. Article
  2. Review
  3. Article
  4. Review
  5. Article
  6. Article
  7. Review
  8. Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

11 authors.

Shiyan WangCollege of Electronic and Optical Engineering & College of Flexible Electronics (Future Technology), State Key Laboratory of Flexible Electronics, Nanjing University of Posts and Telecommunications Nanjing 210023 China wanglonglu@njupt.edu.cn iamqzhao@njupt.edu.cn.
Chaopeng LiuCollege of Electronic and Optical Engineering & College of Flexible Electronics (Future Technology), State Key Laboratory of Flexible Electronics, Nanjing University of Posts and Telecommunications Nanjing 210023 China wanglonglu@njupt.edu.cn iamqzhao@njupt.edu.cn.
Weiyao HaoCollege of Electronic and Optical Engineering & College of Flexible Electronics (Future Technology), State Key Laboratory of Flexible Electronics, Nanjing University of Posts and Telecommunications Nanjing 210023 China wanglonglu@njupt.edu.cn iamqzhao@njupt.edu.cn.
Yanling ZhuangCollege of Electronic and Optical Engineering & College of Flexible Electronics (Future Technology), State Key Laboratory of Flexible Electronics, Nanjing University of Posts and Telecommunications Nanjing 210023 China wanglonglu@njupt.edu.cn iamqzhao@njupt.edu.cn.
Jianmei ChenCollege of Electronic and Optical Engineering & College of Flexible Electronics (Future Technology), State Key Laboratory of Flexible Electronics, Nanjing University of Posts and Telecommunications Nanjing 210023 China wanglonglu@njupt.edu.cn iamqzhao@njupt.edu.cn.
Xianjun ZhuCollege of Electronic and Optical Engineering & College of Flexible Electronics (Future Technology), State Key Laboratory of Flexible Electronics, Nanjing University of Posts and Telecommunications Nanjing 210023 China wanglonglu@njupt.edu.cn iamqzhao@njupt.edu.cn.
Longlu WangCollege of Electronic and Optical Engineering & College of Flexible Electronics (Future Technology), State Key Laboratory of Flexible Electronics, Nanjing University of Posts and Telecommunications Nanjing 210023 China wanglonglu@njupt.edu.cn iamqzhao@njupt.edu.cn.
Xianghong NiuCollege of Science, Nanjing University of Posts and Telecommunications Nanjing 210023 China.ORCID https://orcid.org/0000-0001-6475-8839
Jianjun MaoDepartment of Physics, Shanghai Normal University Shanghai 200232 China jjmao@shnu.edu.cn.
Dongwei MaSchool of Physics and Electronic Information, Huaibei Normal University Huaibei 235000 China dwmachina@126.com.ORCID https://orcid.org/0000-0002-6014-567X
Qiang ZhaoCollege of Electronic and Optical Engineering & College of Flexible Electronics (Future Technology), State Key Laboratory of Flexible Electronics, Nanjing University of Posts and Telecommunications Nanjing 210023 China wanglonglu@njupt.edu.cn iamqzhao@njupt.edu.cn.ORCID https://orcid.org/0000-0002-3788-4757

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The structural evolution of metal single-atoms and clusters has been recognized as the new frontier in catalytic reactions under operative conditions, playing a crucial role in key aspects of catalytic behavior, including activity, selectivity, stability, and atomic efficiency as well as precise tunability in heterogeneous catalysis. Accurately identifying the structural evolution of metal single-atoms and clusters during real reactions is essential for addressing fundamental issues such as active sites, metal-support interactions, deactivation mechanisms, and thereby guiding the design and fabrication of high-performance single-atom and cluster catalysts. However, how to evaluate the dynamic structural evolution of metal species during catalytic reactions is still lacking, hindering their industrial applications. In this review, we discuss the behaviors of dynamic structural evolution between metal single-atoms and clusters, explore the driving force and major factors, highlight the challenges and inherent limitations encountered, and present relevant future research trends. Overall, this review provides valuable insights that can inspire researchers to develop novel and efficient strategies for accurately identifying the structural transformations of metal single-atoms and clusters.

Identifiers

PMID40144500
PMCPMC11934265

What OpenQuestion holds

Textmetadata
LicenceCC BY-NC
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.