Evidence map›Paper›PMID 40142085›Full record

ReviewMolecules (Basel, Switzerland)2025

Mechanistic Insights into Glycerol Oxidation to High-Value Chemicals via Metal-Based Catalysts.

Junqing Li, Ying Tu, Kelin He, Chao Chen, Lixing Liang, Chongze Ruan, Qitao Zhang

Abstract readReview
In one paragraph

Review in Molecules (Basel, Switzerland), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

  1. Photoelectrochemical HChemical science · 2026
    Review
  2. Review
  3. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Junqing LiInternational Collaborative Laboratory of 2D Materials for Optoelectronics Science and Technology of Ministry of Education, Institute of Microscale Optoelectronics, Shenzhen University, Shenzhen 518000, China.
Ying TuInternational Collaborative Laboratory of 2D Materials for Optoelectronics Science and Technology of Ministry of Education, Institute of Microscale Optoelectronics, Shenzhen University, Shenzhen 518000, China.
Kelin HeInternational Collaborative Laboratory of 2D Materials for Optoelectronics Science and Technology of Ministry of Education, Institute of Microscale Optoelectronics, Shenzhen University, Shenzhen 518000, China.
Chao ChenInternational Collaborative Laboratory of 2D Materials for Optoelectronics Science and Technology of Ministry of Education, Institute of Microscale Optoelectronics, Shenzhen University, Shenzhen 518000, China.
Lixing LiangCollege of Materials and Energy, South China Agricultural University, Guangzhou 510642, China.
Chongze RuanCollege of Materials and Energy, South China Agricultural University, Guangzhou 510642, China.ORCID 0009-0004-6688-132X
Qitao ZhangInternational Collaborative Laboratory of 2D Materials for Optoelectronics Science and Technology of Ministry of Education, Institute of Microscale Optoelectronics, Shenzhen University, Shenzhen 518000, China.ORCID 0000-0002-8817-0033

Funding

the Guangdong Basic and Applied Basic Research Foundation 2024A1515010976the Postdoctoral Fellowship Program of CPSF GZC20241085the Shenzhen Peacock Plan 20210802524B
6 · The paper itself

Abstract

The oxidation of glycerol offers a valuable route for producing high-value chemicals. This review provides an in-depth analysis of the current advancements and mechanistic insights into novel metal-based catalysts for glycerol oxidation. We discuss the catalytic roles of both precious metals (e.g., Pt, Pd, Au), noted for their high efficiency and selectivity, and cost-effective alternatives, such as Ni, Cu, and Fe. Bimetallic and metal oxide catalysts are highlighted, emphasizing synergistic effects that enhance catalytic performance. This review elucidates the key mechanism involving selective adsorption and oxidation, providing detailed insights from advanced spectroscopic and computational studies into the activation of glycerol and stabilization of key intermediates, including glyceraldehyde and dihydroxyacetone. Additionally, selective carbon-carbon bond cleavage to yield smaller, valuable molecules is addressed. Finally, we outline future research directions, emphasizing the development of innovative catalysts, deeper mechanistic understanding, and sustainable process scale-up, ultimately advancing efficient, selective, and environmentally friendly catalytic systems for glycerol valorization.

Indexed as

glycerol selectivity oxidationhigh-value chemicalsmechanistic pathwaysmetal-based catalysts

Identifiers

PMID40142085
PMCPMC11945027

What OpenQuestion holds

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LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.