Preparation and Properties of PETG Filament Modified with a Metallic Additive.

The materials used as filaments for additive techniques should exhibit various properties depending on the application and the requirements. The motivation for this study was the need to obtain a filament exhibiting appropriate aesthetic (metal-like) and mechanical properties. Glycol-modified poly(ethylene terephthalate) copolymer (PETG) and micrometric steel powder were used for composite preparation. Subsequently, the obtained material was used as a filament for 3D printing, i.e., by fused deposition modeling (FDM) technique. The physicochemical properties of the obtained filaments were determined, such as morphology (roughness), moisture sorption ability, thermal properties, and mechanical performance (tensile and compressive strength). Importantly, the metal filler did not modify the thermal properties of the polyester matrix, indicating that the filament containing steel microfiller could be processed using the same parameters as for neat PETG. The thermal stability was slightly enhanced after steel powder addition (for 13 wt.% content, the temperature of 75% weight loss was 466 °C; for comparison, that for the reference sample was 446 °C). The reinforcing effect of steel microfiller was noted based on mechanical performance measurements. The steel particles acted as a stiffening agent; the highest maximal tensile strength was observed for the composite with 3 wt.% steel powder content (ca. 68 MPa). Further increasing the microfiller load resulted in a slight decrease in the value of this parameter. A different trend was reported considering the compressive strength, i.e., the value of this parameter increased with steel content. Based on the obtained results, the new PETG composites could be applied as structural materials.