Tuning the Properties of Dodecylpyridinium Metallosurfactants: The Role of Iron-Based Counterions.

Mirta Rubčić, Mirta Herak, Ana Ivančić, Edi Topić, Emma Beriša, Ivana Tartaro Bujak, Darija Domazet Jurašin

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Article in International journal of molecular sciences, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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7 authors.

Mirta RubčićDepartment of Chemistry, Faculty of Science, University of Zagreb, Horvatovac 102a, HR-10000 Zagreb, Croatia.

Mirta HerakDepartment for Research of Materials Under Extreme Conditions, Institute of Physics, Bijenička Cesta 46, HR-10000 Zagreb, Croatia.

Ana IvančićDivision of Physical Chemistry, Ruđer Bošković Institute, Bijenička 54, HR-10000 Zagreb, Croatia.

Edi TopićDepartment of Chemistry, Faculty of Science, University of Zagreb, Horvatovac 102a, HR-10000 Zagreb, Croatia.ORCID 0000-0002-7184-7757

Emma BerišaFaculty of Chemical Engineering and Technology, University of Zagreb, Trg Marka Marulića 19, HR-10000 Zagreb, Croatia.

Ivana Tartaro BujakDivision of Materials Chemistry, Ruđer Bošković Institute, Bijenička 54, HR-10000 Zagreb, Croatia.ORCID 0000-0002-1396-164X

Darija Domazet JurašinDivision of Physical Chemistry, Ruđer Bošković Institute, Bijenička 54, HR-10000 Zagreb, Croatia.ORCID 0000-0001-5261-5961

Funding

Croatian Science Foundation IP-2024-05-3668European Union's Horizon 101057961

6 · The paper itself

Abstract

Metallosurfactants combine the unique soft-matter properties of surfactants with magnetic functionalities of metal ions. The inclusion of iron-based species, in particular, can further boost the functionality of the material, owing to iron's ability to adopt multiple oxidation states and form both high-spin and low-spin complexes. Motivated by this, a series of hybrid inorganic-organic dodecylpyridinium metallosurfactants with iron-containing counterions was developed. It was established that using either divalent or trivalent iron halides in a straightforward synthetic procedure yields C

Indexed as

IronPyridinium CompoundsSurface-Active AgentsIronPyridinium CompoundsSurface-Active Agentscrystal structureinorganic-organic hybridsionic liquidsiron complexeslow-dimensional magnetsmetallosurfactantsself-assemblysolid-state magnetism

Identifiers

PMID40141184

DOI10.3390/ijms26062540

PMCPMC11942540

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