Improved Prediction of Elastic Modulus for Carbon-Based Aerogels Using Power-Scaling Model.

The mechanical stability of carbon aerogels, particularly their thermal insulation performance, is closely linked to their elastic modulus. This property plays a crucial role in determining the material's overall mechanical stability. The objective of this study is to enhance the accuracy of elastic modulus predictions for carbon aerogels using a power-scaling model. By setting the prefactor of the Gibson and Ashby equation to 1.0, accurate predictions of the elastic modulus can be achieved if the correct scaling exponent is determined. Twelve sets of experimental data were used to fit the power-scaling model, revealing that the scaling exponent for the elastic modulus of carbon aerogels typically falls between 2.2 and 3.0. This range is narrower than the 2.0 to 4.0 range reported in the literature, with a median value of 2.6 providing reliable predictions. Additionally, a relationship between the solid thermal conductivity and the elastic modulus of carbon aerogels was established using a thermal conduction model. The study also examined the elastic modulus of carbon nanotube and graphene aerogels-both allotropes of carbon aerogel. By fitting experimental data into the power-scaling model, the scaling exponents for carbon nanotube aerogels and graphene aerogels were found to range from 2.7 to 3.5 and 2.7 to 3.7, respectively. Median exponent values of 3.1 and 3.2 were identified as optimal for predicting the elastic moduli of carbon nanotube and graphene aerogels.