ArticleMacromolecular rapid communications2025
A Novel Synthesis Strategy for Poly(Arylene-Vinylene) Derivatives by Elemental Sulfur-Mediated Polyolefination.
Article in Macromolecular rapid communications, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
1 citing paper in PubMed.
- A Novel Synthesis Strategy for Poly(Arylene-Vinylene) Derivatives by Elemental Sulfur-Mediated Polyolefination.Macromolecular rapid communications · 2025Article
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4 authors.
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Abstract
Herein, a new synthetic access to poly(arylene-1,2-diarylvinylene) (PAV-DA) derivatives is presented by a novel polyolefination of bifunctional N-tosylhydrazones using base-activated elemental sulfur. PAV-DAs are particularly interesting due to their aggregation-induced emission (AIE) properties, resulting in high solid-state photoluminescence quantum yields. The presented procedure allows the successful synthesis of eight homopolymers and two copolymers with different arylene backbones and aryl side chains from easily accessible monomers, not requiring the use of expensive or highly hazardous materials. The polymers are obtained in good yields and number average molecular weights up to 26.9 kDa. Thermal analysis reveals exceptionally high thermal stability with degradation temperatures as high as 541 °C and glass transition temperatures of up to 263 °C. Furthermore, it is found that the polymer properties are easily adjustable via copolymerization.
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