Evidence map›Paper›PMID 40123235›Full record

ArticleJournal of the American Chemical Society2025

Acylphosphine Route to Colloidal InP Quantum Dots.

Andriy Stelmakh, Georgios Marnieros, Erik Schrader, Georgian Nedelcu, Oleh Hordiichuk, Eduard Rusanov, Ihor Cherniukh, Daniel Zindel, Hansjörg Grützmacher, Maksym V Kovalenko

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Journal of the American Chemical Society, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

  1. Review
  2. Review
  3. Tribenzoylarsine - A Benign Arsenic Precursor for InAs Nanocrystals.Small (Weinheim an der Bergstrasse, Germany) · 2025
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

10 authors.

Andriy StelmakhLaboratory of Inorganic Chemistry, Department of Chemistry and Applied Biosciences, ETH Zürich, Vladimir Prelog Weg 1, Zürich CH-8093, Switzerland.ORCID 0000-0002-6898-1816
Georgios MarnierosLaboratory of Inorganic Chemistry, Department of Chemistry and Applied Biosciences, ETH Zürich, Vladimir Prelog Weg 1, Zürich CH-8093, Switzerland.ORCID 0009-0000-3202-5948
Erik SchraderLaboratory of Inorganic Chemistry, Department of Chemistry and Applied Biosciences, ETH Zürich, Vladimir Prelog Weg 1, Zürich CH-8093, Switzerland.
Georgian NedelcuLaboratory of Inorganic Chemistry, Department of Chemistry and Applied Biosciences, ETH Zürich, Vladimir Prelog Weg 1, Zürich CH-8093, Switzerland.
Oleh HordiichukLaboratory of Inorganic Chemistry, Department of Chemistry and Applied Biosciences, ETH Zürich, Vladimir Prelog Weg 1, Zürich CH-8093, Switzerland.ORCID 0000-0001-7679-4423
Eduard RusanovLaboratory of Inorganic Chemistry, Department of Chemistry and Applied Biosciences, ETH Zürich, Vladimir Prelog Weg 1, Zürich CH-8093, Switzerland.
Ihor CherniukhLaboratory of Inorganic Chemistry, Department of Chemistry and Applied Biosciences, ETH Zürich, Vladimir Prelog Weg 1, Zürich CH-8093, Switzerland.ORCID 0000-0001-7155-5095
Daniel ZindelLaboratory of Physical Chemistry, Department of Chemistry and Applied Biosciences, ETH Zürich, Vladimir Prelog Weg 2, Zürich CH-8093, Switzerland.
Hansjörg GrützmacherLaboratory of Inorganic Chemistry, Department of Chemistry and Applied Biosciences, ETH Zürich, Vladimir Prelog Weg 1, Zürich CH-8093, Switzerland.
Maksym V KovalenkoLaboratory of Inorganic Chemistry, Department of Chemistry and Applied Biosciences, ETH Zürich, Vladimir Prelog Weg 1, Zürich CH-8093, Switzerland.ORCID 0000-0002-6396-8938

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

InP-based quantum dots (QDs) represent the major commercial success of colloidal semiconductor nanocrystals (NCs). A combination of the robust, mostly covalent, structure and nontoxic nature of the constituent elements makes them a QD material of choice for display and LED technologies. Despite successful commercial realization, InP NCs still lack synthetic versatility and robustness, seen, for instance, as a continued quest to substitute a commonly used pyrophoric and expensive tris(trimethylsilyl)phosphine precursor. Herein, we propose solid-state, nonpyrophoric, and synthetically readily accessible acylphosphines as convenient phosphorus precursors for the synthesis of InP NCs. When combined with suitable anionic nucleophiles, such as arylthiolates, both tris(acyl)phosphines and indium complexes of bis(acyl)phosphines act as efficient sources of the P

Identifiers

PMID40123235
PMCPMC11969539

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.