ArticleNature communications2025
A bipolar-redox tetraalkynylporphyrin macrocycle positive electrode with 12-electrons-transfer for high-energy aluminum-organic batteries.
Article in Nature communications, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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Who cites it
3 citing papers in PubMed.
- Durable and Self-Charging Aluminum-Organic Battery Based on Conjugated Ladder Polymer.Small (Weinheim an der Bergstrasse, Germany) · 2026Article
- Metalloporphyrin-Based Cathode for Rechargeable Magnesium-Ion Batteries: Copper Leaching and Interphase Formation.ChemSusChem · 2026Article
- Redox Oligomer Assembling Hierarchical Reinforced Framework Cathodes for Ultra-Stable High-Performance Zinc-Ion Batteries.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
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Authors and funding
9 authors.
Funding
Abstract
Organic electrode materials with bipolar-redox activity are a promising candidate for high-energy aluminum-ion batteries (AIBs), but face the capacity ceiling due to limited active sites and low electron transfer number. To universally address this issue, seeking for a kind of multisite bipolar organic material to achieve multielectron transfer is a prerequisite but challenging. Herein, we develop a 12-electron transfer tetraalkynylporphyrin macrocycle positive electrode with two p-type amine (‒NH‒) motifs, two n-type imine (C = N) motifs and four n-type alkynyl (C ≡ C) motifs. The bipolar 18π-electron porphyrin macrocycle can alternately bind and release AlCl
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Registered trials
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