ArticleNature communications2025
Fluorinated amorphous halides with improved ionic conduction and stability for all-solid-state sodium-ion batteries.
Article in Nature communications, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.
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Who cites it
10 citing papers in PubMed.
- Fluorine-Free Strategies for Sustainable Batteries.ChemSusChem · 2026Review
- Chloride-Regulated Depolymerization of Aluminosilicate Networks for Fast Ion Transport Compliant Interfaces in Sustainable All-Solid-State Sodium Batteries.Angewandte Chemie (International ed. in English) · 2026Article
- Unraveling Bridging-Oxygen-Driven Ultrafast Amorphization in Superionic Oxyhalide Conductors via in Situ Synchrotron X-Ray Scattering.Angewandte Chemie (International ed. in English) · 2026Article
- Energetic All-Polymer Fiber Batteries Enabled by Interface-Interlocked Water-In-Network Electrolytes for Wearable Electronics.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Anion-exchange fluorinated ion conductors for stable high-voltage lithium battery.Nature communications · 2026Article
- Challenges and advances of sulfide solid electrolytes for high-energy-density sodium metal batteries.Chemical science · 2026Review
- Interfacial Stability and Design Strategies for Halide Solid Electrolytes in High-Voltage All-Solid-State Sodium-Ion Batteries.Small methods · 2026Article
- Redox-Active Halide Catholytes for Solid-State Lithium Batteries.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Review
- Structure and Ionic Conductivity of Halide Solid Electrolytes Based on NaAlClAdvanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Powering the Future: Unveiling the Potential of Na, K, and Mg Solid-State Batteries.Nanomaterials (Basel, Switzerland) · 2025Review
Corrections and comments
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Authors and funding
9 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Designing halide solid electrolytes with high ionic conductivity and good (electro)chemical stability is essential for the advancement of all-solid-state sodium-ion batteries. Unfortunately, most sodium-based halide solid electrolytes experience limited ionic conductivities and ambiguous correlations between their structure features and ion transport properties. Here we report a design strategy to boost the conductivities of sodium halides by regulating vacancy and charge carrier concentrations through a facile Na- and Cl-deficient compositions method. This approach achieves a balanced structure with optimal vacancy and carrier content, rendering several-fold conductivities enhancement of series sodium halides. Furthermore, a fluorination-induced amorphization protocol is employed to enhance (electro)chemical stability and interfacial compatibility without detrimentally influencing conductivities. The promoted conductivities of the fluorinated sample are primarily due to increased local structural disorder and enhanced prismatic Na coordination. When paired with an uncoated Na
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Registered trials
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